(а) (b) (c) нн ОН ОН нн ОН нн ОН DH LOH D D DH OD нн OH PCC Н NaBD4 EtOH OH D Н

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Add'n of hydride (H:-): ROH prep. by reduction of C=O compounds
[C=O→CH-OH] (17.3-17.5)
(a)
(b)
Recall: D = deuterium; an isotope of hydrogen
Practice problem: show the synthetic steps involved to perform the following transformations.
Proposed synthesis
change in oxid. state permits add'n of D
(c)
OH
Η Η
OH
Η Η
OH
Η Η
OH
DH
OH
D D
OD
DH
OH PCC
HH
H
NaBD4
EtOH
(chap. 17 & 18)
OH
DH
31
Transcribed Image Text:Add'n of hydride (H:-): ROH prep. by reduction of C=O compounds [C=O→CH-OH] (17.3-17.5) (a) (b) Recall: D = deuterium; an isotope of hydrogen Practice problem: show the synthetic steps involved to perform the following transformations. Proposed synthesis change in oxid. state permits add'n of D (c) OH Η Η OH Η Η OH Η Η OH DH OH D D OD DH OH PCC HH H NaBD4 EtOH (chap. 17 & 18) OH DH 31
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