A B Br CI (45)-4-chlorc (3R)-3-chlord (3S)-3-chlora 4R-4-chlorc

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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1. Choose the correct IUPAC name for A
2. Choose the correct IUPAC name for B [Select]
[Select]
A
B
Br
Cl
(45)-4-chloro-3-methylhexane
(3R)-3-chloro-4-methylhexane
(35)-3-chloro-4-methylhexane
(4R)-4-chloro-3-methylhexane
Transcribed Image Text:To preview image click here 1. Choose the correct IUPAC name for A 2. Choose the correct IUPAC name for B [Select] [Select] A B Br Cl (45)-4-chloro-3-methylhexane (3R)-3-chloro-4-methylhexane (35)-3-chloro-4-methylhexane (4R)-4-chloro-3-methylhexane
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1. Choose the correct IUPAC name for A [Select]
[Select]
(1R.3R)-1-bromo-3-methylcyclohexane
2. Choose the correct IUPAC name for B (15.3R)-1-bromo-3-methylcyclohexane
(1S,3S)-1-bromo-3-methylcyclohexane
(1R,3S)-1-bromo-3-methylcyclohexane
A
B
Br
CI
Transcribed Image Text:To preview image click here 1. Choose the correct IUPAC name for A [Select] [Select] (1R.3R)-1-bromo-3-methylcyclohexane 2. Choose the correct IUPAC name for B (15.3R)-1-bromo-3-methylcyclohexane (1S,3S)-1-bromo-3-methylcyclohexane (1R,3S)-1-bromo-3-methylcyclohexane A B Br CI
Expert Solution
Step 1: Rules for IUPAC naming

Identify the Longest Carbon Chain: Find the longest continuous chain of carbon atoms (the parent chain) in the molecule. This chain serves as the backbone of the name.

Number the Carbon Atoms: Number the carbon atoms in the parent chain starting from the end nearest to a substituent or functional group. This ensures the lowest possible numbers for substituents.

Name Substituents: Identify and name any substituent groups attached to the parent chain. Use prefixes like "methyl," "ethyl," "chloro," etc., to indicate these groups. Number them based on their positions in the parent chain.

Indicate Multiple Bonds: Use the prefixes "ene" for double bonds and "yne" for triple bonds. Indicate the position of multiple bonds by specifying the carbon atom numbers involved.

Include Functional Groups: If the molecule contains functional groups, name them according to their priority. Common functional groups include alcohols, aldehydes, ketones, carboxylic acids, and amines. Use suffixes like "ol," "al," "one," "oic acid," and "amine" for these groups, respectively.

Use Hyphens and Commas: Separate numbers by hyphens when indicating the position of substituents or multiple bonds. Use commas to separate numbers when there are multiple substituents of the same kind.

Alphabetize Substituents: List substituents in alphabetical order when naming a compound. Ignore prefixes like "di-" or "tri-" when alphabetizing.

Remove Spaces: Do not include spaces in the compound name. Use hyphens to separate words within the name.

Use Numerical Prefixes: Use numerical prefixes like "di-" (2), "tri-" (3), "tetra-" (4), etc., to indicate the number of identical substituents or functional groups.

Identify Stereochemistry: If the compound has stereoisomers, use prefixes like "cis-" and "trans-" or "R" and "S" for chiral compounds to indicate stereochemistry.

Name Cyclic Compounds: For cyclic compounds, identify the ring and its substituents, following the same rules for naming substituents and numbering the carbons in the ring.

Use Proper Suffixes: Use appropriate suffixes such as "-ane" for alkanes, "-ene" for alkenes, "-yne" for alkynes, etc., to indicate the class of hydrocarbon.

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