A) A vessel at STP contains 28.5 kg of N2 (molecular mass = 28u). What is the mean free path of the N2 molecules in the vessel? An N2 molecule has a diameter of 3x10-10 m.

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**Problem Statement:**

A vessel at Standard Temperature and Pressure (STP) contains 28.5 kg of nitrogen gas (N₂) with a molecular mass of 28u (atomic mass units). What is the mean free path of the N₂ molecules in the vessel? An N₂ molecule has a diameter of 3 x 10⁻¹⁰ m.

**Solution Explanation:**

To find the mean free path of the nitrogen molecules, you need to understand the following concepts:

1. **Mean Free Path (λ):** The average distance traveled by a molecule between collisions. 
2. **Formula for Mean Free Path:**
   \[
   \lambda = \frac{k_B \cdot T}{\sqrt{2} \cdot \pi \cdot d^2 \cdot P}
   \]
   Where:
   - \( k_B \) is the Boltzmann constant (\(1.38 \times 10^{-23} \text{ J/K} \))
   - \( T \) is the temperature in Kelvin
   - \( d \) is the diameter of a molecule (given as \(3 \times 10^{-10} \) m)
   - \( P \) is the pressure in Pascals (at STP, \( P = 1.013 \times 10^5 \) Pa)
   - \( \pi \) is a constant (approximately 3.14159)

3. **Parameters at STP:**
   - Temperature (\( T \) = 273.15 K)
   - Pressure (\( P = 1.013 \times 10^5 \) Pa)

Plug the respective values into the formula to find the mean free path of N₂ molecules in the vessel.

By understanding these concepts, one can calculate physical properties like the mean free path which is crucial for understanding molecular dynamics in gases.
Transcribed Image Text:**Problem Statement:** A vessel at Standard Temperature and Pressure (STP) contains 28.5 kg of nitrogen gas (N₂) with a molecular mass of 28u (atomic mass units). What is the mean free path of the N₂ molecules in the vessel? An N₂ molecule has a diameter of 3 x 10⁻¹⁰ m. **Solution Explanation:** To find the mean free path of the nitrogen molecules, you need to understand the following concepts: 1. **Mean Free Path (λ):** The average distance traveled by a molecule between collisions. 2. **Formula for Mean Free Path:** \[ \lambda = \frac{k_B \cdot T}{\sqrt{2} \cdot \pi \cdot d^2 \cdot P} \] Where: - \( k_B \) is the Boltzmann constant (\(1.38 \times 10^{-23} \text{ J/K} \)) - \( T \) is the temperature in Kelvin - \( d \) is the diameter of a molecule (given as \(3 \times 10^{-10} \) m) - \( P \) is the pressure in Pascals (at STP, \( P = 1.013 \times 10^5 \) Pa) - \( \pi \) is a constant (approximately 3.14159) 3. **Parameters at STP:** - Temperature (\( T \) = 273.15 K) - Pressure (\( P = 1.013 \times 10^5 \) Pa) Plug the respective values into the formula to find the mean free path of N₂ molecules in the vessel. By understanding these concepts, one can calculate physical properties like the mean free path which is crucial for understanding molecular dynamics in gases.
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