(a) A certain first-order reaction has an activation energy of 53 kJ mol-!. It is run twice, first at 298 K and then at 308 K (10°C higher). All other conditions are iden- tical. Show that, in the second run, the reaction occurs at double its rate in the first run. (b) The same reaction is run twice more at 398 K and 408 K. Show that the reaction goes 1.5 times as fast at 408 K as it does at 398 K.
(a) A certain first-order reaction has an activation energy of 53 kJ mol-!. It is run twice, first at 298 K and then at 308 K (10°C higher). All other conditions are iden- tical. Show that, in the second run, the reaction occurs at double its rate in the first run. (b) The same reaction is run twice more at 398 K and 408 K. Show that the reaction goes 1.5 times as fast at 408 K as it does at 398 K.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:(a) A certain first-order reaction has an activation energy
of 53 kJ mol-!. It is run twice, first at 298 K and then
at 308 K (10°C higher). All other conditions are iden-
tical. Show that, in the second run, the reaction occurs
at double its rate in the first run.
(b) The same reaction is run twice more at 398 K and
408 K. Show that the reaction goes 1.5 times as fast at
408 K as it does at 398 K.
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