A 575-mL sample of nitrogen has a pressure of 720 Torr at 27oC. a. What will be the new volume if the temperature is raised to 77oC, while the pressure is maintained (i.e., 720 Torr)?    ____________ mL b. What will be the new volume if the pressure is raised to 780 Torr, while the original temperature is maintained (i.e., 27oC)?     ____________ mL c. What will be the new volume if the pressure is raised to 780 Torr and the temperature is raised to 77oC?

Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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A 575-mL sample of nitrogen has a pressure of 720 Torr at 27oC.


a. What will be the new volume if the temperature is raised to 77oC,
while the pressure is maintained (i.e., 720 Torr)?    ____________ mL


b. What will be the new volume if the pressure is raised to 780 Torr,
while the original temperature is maintained (i.e., 27oC)?     ____________ mL


c. What will be the new volume if the pressure is raised to 780 Torr
and the temperature is raised to 77oC?

Expert Solution
Step 1

According to ideal gas law,

PV = nRT

where P = pressure

V = volume

n = moles

R = gas constant = 0.0821 atm.L/K.mol

T = temperature in K = T in °C + 273

Step 2

a) Since the pressure is kept constant and also amount of gas is not changing. Hence P and n are constant.

Chemistry homework question answer, step 2, image 1

Hence we can say 

Chemistry homework question answer, step 2, image 2

where Vinitial = initial volume = 575 mL and  Tinitial = initial temperature in K = 273 + 27 = 300 K

and Vfinal = final volume and  Tfinal = final temperature in K = 273 + 77 = 350 K 

Hence substituting the values we get 

Chemistry homework question answer, step 2, image 3

=> Vfinal = 670.8 mL approx = the new volume

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