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A 50.0 mL of 0.20 M ascorbic acid (see Appendix) is titrated with a 0.20 M NaOH solution. Calculate the volume of NaOH solution added when he pH of solution is a) 3.04 b) 5.65

A 50.0 mL of 0.20 M ascorbic acid (see Appendix) is titrated with a 0.20 M NaOH solution. Calculate the volume of NaOH solution added when he pH of solution is a) 3.04 b) 5.65

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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A 50.0 mL of 0.20 M ascorbic acid (see Appendix) is titrated with a 0.20 M NaOH solution. Calculate
the volume of NaOH solution added when he pH of solution is
a) 3.04
b) 5.65

Table of Acids with Ka and oKa values Acid HA Ka pka Hydroniun ion lodic Oxalic (1) Sulfurous (1) Sulfuric (2) Chlorous Phosphoric (1) Arsenic (1) Chloroacetic Citric (1) HO HIO, HCO H,SO, HSO, HCIO, HIPO, H;AsO, CH;CICOOH HCH,O, HO 0.0 1.6x 10 5.9 x 10 1.54 x 10 12x 10 1.1 x 10 7.52 x 10 5.0 x 10 14x 10 8.4 x 10 10 HC O 0.50 1.23 1.81 HSO, SO 1.92 CIO H;PO, HASO, CH,CICOO 1.96 2.12 230 285 3.08 7.2x 10 4.0 x 10 1.77 x 10 1.38 x 10 7.9 x 10 6.46 x 10 6.4 x 10 1.9 x 10 1.8x 10 Hydrofluoric HF 3.14 Nitrous HNO, HCOOH HCH,HO NO HCOO CH HO HCHO CHCO0 CO, 3,39 Formic Lactic 3.75 3.86 Ascorbic (1) Benzoie Oxalic (2) Hydrazoic Citric (2) 4.10 CH,COOH HC O HN; 4.19 4.19 4.72 HCH;O, CH;CO0 CH;CH CO0 CHN CH,O, HCO So HASO, 4.74 CH COOH CH;CH,COOH CHẠNH HC H.O H-CO HSO, HASO H;S Acetic 1.76 x 10 4.75 134 x 10 5.6x 10 4.0 x 10 43 x 10" 1.02 x 10 8/9.3 x 10 10x 109.1 x 10 Propionic Pyridinitm ion Citric (3) Carbonic (1) Sulfurous (2) Arsenic (2) Hydrosulfuric Phosphoric (2) Hypochlorous Hypobromous Hydrocyanic Boric (1) Ammonium ion Phenol 4.87 5.25 5.40 6.37 6.91 7.10/7.03 HS 7/7.04 6.23 x 10 3.5/3.0 x 10 2x 10 6.17 x 10 5.8x 10 3.6x 10 1.6x 10 4.8x 10" 2x 10 6.0 x 103.0 x 10 24x 10 1.6x 10 4.8/22x 10 1.0 x 10 HPO, HCIO HPO, 7.21 7.46/7.53 HBro Bro 8.70 HCN CN 9.21 HIBO, NH CHOH HCO, HIO HBO, NH, CHO CO 10 Aso, HO, 9.23 9.25 9.80 Carbonic (2) Hypoiodous Arsenic (3) Hydrogen peroxide Ascorbic (2) Phosphoric (3) 10.32 10.70 HASO, 9.22/11.53 11.62 HCHO HPO, 11.80 PO, 1232/12.66 Water 14.0
Transcribed Image Text:Table of Acids with Ka and oKa values Acid HA Ka pka Hydroniun ion lodic Oxalic (1) Sulfurous (1) Sulfuric (2) Chlorous Phosphoric (1) Arsenic (1) Chloroacetic Citric (1) HO HIO, HCO H,SO, HSO, HCIO, HIPO, H;AsO, CH;CICOOH HCH,O, HO 0.0 1.6x 10 5.9 x 10 1.54 x 10 12x 10 1.1 x 10 7.52 x 10 5.0 x 10 14x 10 8.4 x 10 10 HC O 0.50 1.23 1.81 HSO, SO 1.92 CIO H;PO, HASO, CH,CICOO 1.96 2.12 230 285 3.08 7.2x 10 4.0 x 10 1.77 x 10 1.38 x 10 7.9 x 10 6.46 x 10 6.4 x 10 1.9 x 10 1.8x 10 Hydrofluoric HF 3.14 Nitrous HNO, HCOOH HCH,HO NO HCOO CH HO HCHO CHCO0 CO, 3,39 Formic Lactic 3.75 3.86 Ascorbic (1) Benzoie Oxalic (2) Hydrazoic Citric (2) 4.10 CH,COOH HC O HN; 4.19 4.19 4.72 HCH;O, CH;CO0 CH;CH CO0 CHN CH,O, HCO So HASO, 4.74 CH COOH CH;CH,COOH CHẠNH HC H.O H-CO HSO, HASO H;S Acetic 1.76 x 10 4.75 134 x 10 5.6x 10 4.0 x 10 43 x 10" 1.02 x 10 8/9.3 x 10 10x 109.1 x 10 Propionic Pyridinitm ion Citric (3) Carbonic (1) Sulfurous (2) Arsenic (2) Hydrosulfuric Phosphoric (2) Hypochlorous Hypobromous Hydrocyanic Boric (1) Ammonium ion Phenol 4.87 5.25 5.40 6.37 6.91 7.10/7.03 HS 7/7.04 6.23 x 10 3.5/3.0 x 10 2x 10 6.17 x 10 5.8x 10 3.6x 10 1.6x 10 4.8x 10" 2x 10 6.0 x 103.0 x 10 24x 10 1.6x 10 4.8/22x 10 1.0 x 10 HPO, HCIO HPO, 7.21 7.46/7.53 HBro Bro 8.70 HCN CN 9.21 HIBO, NH CHOH HCO, HIO HBO, NH, CHO CO 10 Aso, HO, 9.23 9.25 9.80 Carbonic (2) Hypoiodous Arsenic (3) Hydrogen peroxide Ascorbic (2) Phosphoric (3) 10.32 10.70 HASO, 9.22/11.53 11.62 HCHO HPO, 11.80 PO, 1232/12.66 Water 14.0
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