A 40.00 ml aliquot of 0.0500 M HNO2 is diluted to 80.0 ml in water and titrated with 0.0800 M Ce4+ to form NO3- and Ce3+. Assume the hydrogen ion concentration is at 1.00 M throughout the titrtion. Use 1.44 Volts as the standard potential for the Ce4+/Ce3+ system and 0.94 Volts for the NO3-/NO2 system. Write and balance the two half-cell reactions Calculate the potential of the indicator electrode with respect to an Ag/AgCl saturated reference electrode after the titration of the HNO2 solution with 5.00, 50.00, 60.00 and 100.00 ml of Ce4+.
A 40.00 ml aliquot of 0.0500 M HNO2 is diluted to 80.0 ml in water and titrated with 0.0800 M Ce4+ to form NO3- and Ce3+. Assume the hydrogen ion concentration is at 1.00 M throughout the titrtion. Use 1.44 Volts as the standard potential for the Ce4+/Ce3+ system and 0.94 Volts for the NO3-/NO2 system. Write and balance the two half-cell reactions Calculate the potential of the indicator electrode with respect to an Ag/AgCl saturated reference electrode after the titration of the HNO2 solution with 5.00, 50.00, 60.00 and 100.00 ml of Ce4+.
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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- A 40.00 ml aliquot of 0.0500 M HNO2 is diluted to 80.0 ml in water and titrated with 0.0800 M Ce4+ to form NO3- and Ce3+. Assume the hydrogen ion concentration is at 1.00 M throughout the titrtion. Use 1.44 Volts as the standard potential for the Ce4+/Ce3+ system and 0.94 Volts for the NO3-/NO2 system.
- Write and balance the two half-cell reactions
- Calculate the potential of the indicator electrode with respect to an Ag/AgCl saturated reference electrode after the titration of the HNO2 solution with 5.00, 50.00, 60.00 and 100.00 ml of Ce4+.
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VIEWStep 5: Calculation of potential after the addition of 50.00 mL titrant
VIEWStep 6: Calculation of potential after the addition of 60.00 mL titrant
VIEWStep 7: Calculation of potential after the addition of 100.00 mL titrant
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