Answered: :(a) 3-Methylbutanal (b)…

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:(a) 3-Methylbutanal (b) 3-Methylbut-3-enal(c) 4-Chloropentan-2-one (

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter3: Organic Compounds: Alkanes And Their Stereochemistry

Section3.4: Naming Alkanes

Problem 11P: Give IUPAC names for the following compounds:

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Question

Draw structures corresponding to the following IUPAC names:(a) 3-Methylbutanal (b) 3-Methylbut-3-enal(c) 4-Chloropentan-2-one (d) Phenylacetaldehyde(e) 2,2-Dimethylcyclohexanecarbaldehyde (f ) Cyclohexane-1,3-dione

Predict the products of the reaction of the following substances with CrO3 inaqueous acid:

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Name the following aldehydes and ketones: (a) (b) CH2CH2CHO CH3CH2CCHCH3 CH3 Draw structures corresponding to the following names: (b) 4-Chloropentan-2-one (e) 3-Methylbut-3-enal
Draw the line structures and provide common names for the following ketones: (a) 1-Phenylpropanone (b) 2-Methylpentan-3-one(c) 1-Cyclohexyl-3,3-dimethylbutan-2-one
Name and draw the products of each reaction. 1-propanol + hydrobromic acid → (a) (b) 1-pentanol H-SO A (c) N-propylmethanamide + water (d) 3-methyl oct-2-ene + hydrochloric acid -
Draw structures corresponding to the following IUPAC names: (a) 2-Methylhexan-2-ol (b) Hexane-1,5-diol (c) 2-Ethylbut-2-en-1-ol (d) Cyclohex-3-en-1-ol (e) o-Bromophenol (f ) 2,4,6-Trinitrophenol
Draw structural formulas for these ketones. (a) Ethyl isopropyl ketone (b) 2-Chlorocyclohexanone (c) 2,4-Dimethyl-3-pentanone (d) Diisopropyl ketone (e) Acetone (f) 2,5-Dimethylcyclohexanone
Citronellol ((3R)-3,7-dimethyloct-6-en-1-ol, C10H20O) is an organic fragrance found in the oil extracted from lemon grass. a) Name the two functional groups present in the molecule. b) When a few drops of bromine dissolved in hexane is added to a sample of citronellol the brown colour of the bromine rapidly disappears. i. What type of chemical reaction has occurred? ii. Draw the structure of the product formed. iii. Name the product. c) The product formed when citronellol is heated with a mixture of potassium dichromate and sulfuric acid gives a yellow/orange precipitate when shaken with Brady’s reagent (2,4-dinitrophenylhydrazine). It also shows a positive result with Fehling’s solution. i. What type of chemical reaction has occurred ? ii. What type of functional group is present in the product? d) Explain the type of stereoisomerism which may occur in citronellol.
Give an IUPAC and common name for each of the following naturally occurring carboxylic acids: (a) CH3CH(OH)CO2H (lactic acid); (b) HOCH2CH2C(OH)(CH3)CH2CO2H (mevalonic acid).
8
Draw out the structures (condensed structural formulas) for the following reactions (reactants and products) and name the product formed. a) Hydrohalogenation of 1,3-dimethylcyclopentene with HBr Name product: b) Hydrogenation of 3,4-dimethylcyclobutene Name product: c) Hydration of 3-ethyl-2-pentene cturslomeo Name product: d) Alkylation of benzene with 2-chloropropane (isopropylchloride) Name product: e) Mono-halogenation of 2,2-dimethylbutane with Cl2 Name product:
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Draw the reaction products of the following reactions of the compound 1-pentanol and name the compounds according to IUPAC! (a) B-elimination of H20 (b) SN reaction in the presence of hydrochloric acid (c) Condensation with acetic acid (d) Oxidation to the corresponding carbonyl compound (e) Condensation of two butanol molecules
for the following compounds, give their IUPAC and common names: