A 100.0 mL sample of 0.300 M NaOH is mixed with a 100.0 mL sample of 0.300 M HCl in a coffee cup calorimeter. If both solutions were initially at 35.00 Celcius and the temperature of the resulting solution was recorded as 37.00 Celcius, determine the Delta H degrees rxn (in units of kJ/mol NaOH) for the neutralization reaction between aqueous NaOH and HCl. Assume 1) that no heat is lost to the calorimeter or the surroundings, and 2) that the density and the heat capacity of the resulting solution are the same as water.
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
A 100.0 mL sample of 0.300 M NaOH is mixed with a 100.0 mL sample of 0.300 M HCl in a coffee cup calorimeter. If both solutions were initially at 35.00 Celcius and the temperature of the resulting solution was recorded as 37.00 Celcius, determine the Delta H degrees rxn (in units of kJ/mol NaOH) for the neutralization reaction between aqueous NaOH and HCl. Assume 1) that no heat is lost to the calorimeter or the surroundings, and 2) that the density and the heat capacity of the resulting solution are the same as water.
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