A 1.171 g sample contains only vitamin C (CH₂O) and sucralose (C₁2H₁9Cl₂ Og). When the sample is dissolved in water to a total volume of 29.1 mL, the osmotic pressure of the solution is 4.57 atm at 295 K. What is the mass percent of vitamin C and sucralose in the sample? vitamin C: % sucralose: %
A 1.171 g sample contains only vitamin C (CH₂O) and sucralose (C₁2H₁9Cl₂ Og). When the sample is dissolved in water to a total volume of 29.1 mL, the osmotic pressure of the solution is 4.57 atm at 295 K. What is the mass percent of vitamin C and sucralose in the sample? vitamin C: % sucralose: %
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![### Determining Mass Percent of Vitamin C and Sucralose from Osmotic Pressure
#### Problem Description:
A 1.171 gram sample contains only two components: Vitamin C (ascorbic acid, chemical formula \( \text{C}_6\text{H}_8\text{O}_6 \)) and sucralose (chemical formula \( \text{C}_{12}\text{H}_{19}\text{Cl}_3\text{O}_8 \)).
When this sample is dissolved in water, making a solution with a total volume of 29.1 mL, the osmotic pressure (\( \pi \)) of the solution is observed to be 4.57 atm at a temperature of 295 K.
The goal is to determine the mass percent of Vitamin C and sucralose in the sample.
#### Required Information:
1. **Osmotic Pressure (\( \pi \))**: The osmotic pressure is given by:
\[
\pi = iCRT
\]
where \( i \) is the van't Hoff factor (assumed to be 1 for non-electrolytes), \( C \) is the molar concentration of the solution, \( R \) is the gas constant (0.0821 L·atm/mol·K), and \( T \) is the temperature in Kelvin.
2. **Molecular Weights**:
- Vitamin C (C₆H₈O₆): \[ 6(12) + 8(1) + 6(16) = 176 \text{ g/mol} \]
- Sucralose (C₁₂H₁₉Cl₃O₈): \[ 12(12) + 19(1) + 3(35.5) + 8(16) = 397.5 \text{ g/mol} \]
#### Calculation Steps:
1. **Calculate Molarity (C)**:
\[
\pi = CRT \implies C = \frac{\pi}{RT} = \frac{4.57 \text{ atm}}{0.0821 \text{ L·atm/mol·K} \times 295 \text{ K}}
\]
2. **Determine Moles of Solute**:
The total moles of solute can be calculated using](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fba6b20c3-fc3b-431b-838d-7e0f9d5cfa41%2F1433af11-eca4-4e24-be2f-8c4ed6e26887%2F9ltck88_processed.png&w=3840&q=75)
Transcribed Image Text:### Determining Mass Percent of Vitamin C and Sucralose from Osmotic Pressure
#### Problem Description:
A 1.171 gram sample contains only two components: Vitamin C (ascorbic acid, chemical formula \( \text{C}_6\text{H}_8\text{O}_6 \)) and sucralose (chemical formula \( \text{C}_{12}\text{H}_{19}\text{Cl}_3\text{O}_8 \)).
When this sample is dissolved in water, making a solution with a total volume of 29.1 mL, the osmotic pressure (\( \pi \)) of the solution is observed to be 4.57 atm at a temperature of 295 K.
The goal is to determine the mass percent of Vitamin C and sucralose in the sample.
#### Required Information:
1. **Osmotic Pressure (\( \pi \))**: The osmotic pressure is given by:
\[
\pi = iCRT
\]
where \( i \) is the van't Hoff factor (assumed to be 1 for non-electrolytes), \( C \) is the molar concentration of the solution, \( R \) is the gas constant (0.0821 L·atm/mol·K), and \( T \) is the temperature in Kelvin.
2. **Molecular Weights**:
- Vitamin C (C₆H₈O₆): \[ 6(12) + 8(1) + 6(16) = 176 \text{ g/mol} \]
- Sucralose (C₁₂H₁₉Cl₃O₈): \[ 12(12) + 19(1) + 3(35.5) + 8(16) = 397.5 \text{ g/mol} \]
#### Calculation Steps:
1. **Calculate Molarity (C)**:
\[
\pi = CRT \implies C = \frac{\pi}{RT} = \frac{4.57 \text{ atm}}{0.0821 \text{ L·atm/mol·K} \times 295 \text{ K}}
\]
2. **Determine Moles of Solute**:
The total moles of solute can be calculated using
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