A 1.077 g sample containing Cu (63.546 g/mol) is analyzed by reducing copper(II) to copper(I) by the reaction of iodide ions. 2Cu2+ + 4I- ⟶ 2CuI + I2 The sample required 15 mL of 0.1000 M Na2S2O3 to react to all the liberated I2 completely. 2S2O32- + I2 ⟶ 2I- + S4O62- What is the %Cu in the sample?

Fundamentals Of Analytical Chemistry
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Chapter17: Complexation And Precipitation Reactions And Titrations
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A 1.077 g sample containing Cu (63.546 g/mol) is analyzed by reducing copper(II) to copper(I) by the reaction of iodide ions.     

   2Cu2+ + 4I- 

 2CuI + I2

The sample required 15 mL of 0.1000 M Na2S2O3 to react to all the liberated I2 completely.

   2S2O32- + I2 

 2I- + S4O62-

What is the %Cu in the sample?

 

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