A 1.000-gram sample of NaOH (39.997 g/mol) which has been exposed to the air for some time (NaOH will adsorb water and CO2 from the ambient air) is dissolved in water and then diluted to 500.00 mL. 100.0 mL of this solution required 38.60 mL of 0.1062 M HCl to be titrated to the endpoint (~pH 3). A second 100.00 mL portion is treated with excess BaCl2 and then diluted to 250 mL and filtered. 200 mL of the filtrate required 29.62 mL of HCl to titrate to the (~pH 8-9) endpoint. Calculate the mass percentage of NaOH and Na2CO3 (105.9898 g/mol) in the original sample. The adsorbed CO2 is converted to Na2CO3. The Ksp for BaCO3 (s) is 2.58 x 10-9.
A 1.000-gram sample of NaOH (39.997 g/mol) which has been exposed to the air for some time (NaOH will adsorb water and CO2 from the ambient air) is dissolved in water and then diluted to 500.00 mL. 100.0 mL of this solution required 38.60 mL of 0.1062 M HCl to be titrated to the endpoint (~pH 3). A second 100.00 mL portion is treated with excess BaCl2 and then diluted to 250 mL and filtered. 200 mL of the filtrate required 29.62 mL of HCl to titrate to the (~pH 8-9) endpoint. Calculate the mass percentage of NaOH and Na2CO3 (105.9898 g/mol) in the original sample. The adsorbed CO2 is converted to Na2CO3. The Ksp for BaCO3 (s) is 2.58 x 10-9.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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A 1.000-gram sample of NaOH (39.997 g/mol) which has been exposed to the air for some time (NaOH will adsorb water and CO2 from the ambient air) is dissolved in water and then diluted to 500.00 mL. 100.0 mL of this solution required 38.60 mL of 0.1062 M HCl to be titrated to the endpoint (~pH 3). A second 100.00 mL portion is treated with excess BaCl2 and then diluted to 250 mL and filtered. 200 mL of the filtrate required 29.62 mL of HCl to titrate to the (~pH 8-9) endpoint. Calculate the mass percentage of NaOH and Na2CO3 (105.9898 g/mol) in the original sample. The adsorbed CO2 is converted to Na2CO3. The Ksp for BaCO3 (s) is 2.58 x 10-9.
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