Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Q 24 please
Expert Solution
Rules for electron filling in orbitals:
1. Aufbau’s principle: According to this principle, the lower energy orbital will be filled before the higher energy orbital. Hence, the order of electron filling will be:
1s < 2s < 2p < 3s < 3p < 4s < 3d < 4p < 5s < 4d < 5p < 6s < 4f < 5d < 6p < and so on
2. Hund’s rule: According to this rule, before pairing electrons in orbitals of a subshell, each orbital should be filled with one electron. The pairing of electrons will occur once all orbitals of a subshell receive a single electron. Example:
Orbitals | px | py | pz |
Electrons(=2) | ↑ | ↑ |
Orbitals | px | py | pz |
Electrons(=3) | ↑ | ↑ | ↑ |
Orbitals | px | py | pz |
Electrons(=4) | ↑↓ | ↑ | ↑ |
3. Pauli Exclusion Principle: According to this principle, two electrons cannot occupy the same orbital with the same spin.
Example:
↑↓ | This is allowed |
↑↑ | This is NOT allowed |
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