A 0.700-g sample is analyzed spectrophotometrically for manganese by dissolving it in acid and transferring to a 250-ml flask and diluting to volume. Three aliquots are analyzed by transferring 50-mL portions with a pipet to 500-mL Erlenmeyer flasks and reacting with an oxidizing agent, potassium peroxydisulfate, to convert the manganese to permanganate. After reaction, these are quantitatively transferred to 250-mL volumetric flasks, diluted to volume, and measured spectrophotometrically. By comparison with standards, the average concentration in the final solution is determined to be 1.25 x 10-5 M. What is the percent manganese in the sample? 3.92% 0.12% 5.10% 0.03%
Q: Use the Henderson-Hasselbalch equation to calculate the pH of a buffer solution prepared by mixing…
A: A mixture of weak acid and its conjugate ion with strong base forms an acidic buffer solution.A…
Q: Problem 1.8 What is the formal charge on the O atom in each of the following species that contains a…
A: Formal charge: The formal charge of an atom in a polyatomic molecule or ion may be defined as the…
Q: For each row in the table below, decide whether the pair of elements will form a molecular or ionic…
A: A molecule compound is formed by the formation of covalent bonds between the atoms. A molecule is…
Q: Highlight all of the carbon atoms that have at least one beta (B) hydrogen, using red for one B…
A: The carbon atom attached to the bromine atom is known as alpha carbon and the adjacent carbon to the…
Q: Draw the major product of this reaction. Ignore inorganic byproducts. 1. BH3-THF 2. H2O2, NaOH
A: Given,The reaction is:
Q: A 33.0 g sample of quartz, which has a specific heat capacity of 0.730 J-g C, is dropped into an…
A: Since water is at higher temperature than quartz therefore heat is transferred from water to quartz…
Q: In the chair conformation of cyclohexane, how many hydrogen atoms are eclipsed? 0 2 4 6 8
A:
Q: Analyze the chemical equation below: C₂H5NH₂ is a CHNH,(m + H_O + C_HNH* is C₂H5NH3*. Its strong…
A: Check that the given compound is weak base and acid. Choose the correct option to complete the…
Q: The absolute stereochemical configuration of (-)-2-octanol is R. Determine which of the following…
A: Absolute stereochemical configuration of (-)-2-octanol is R.Let's find out absolute configuration of…
Q: The voltage generated by the zinc concentration cell described by the line notation Zn(s) | Zn² (aq,…
A: Answer:When same electrolyte is used in both compartments of the cell but with different…
Q: An isotope has 47 protons, 60 neutrons, and 47 electrons. The symbol of this isotope is and its net…
A: Isotopes are members of element that all have the same number of protons but different numbers of…
Q: Three methanol (CH₂OH) molecules are shown below. Which of the labeled interactions are hydrogen…
A: Hydrogen bonding is an attraction force between a more electronegative atom and the electropositive…
Q: A buffer is prepared using the weak acid lactic acid, HC3H5O3, and the salt NaC3H503 containing the…
A: A buffer solution consists of a mixture containing a weak acid and the conjugate base of the weak…
Q: Suppose we have a 1.0M solution of acetic acid, CH,COOH, and a solution of 0.1M hydrochloric acid,…
A: Acidity is defined as the ability of a molecule to release protons. If a compound easily donates…
Q: Antimony is alloyed with lead to increase the rigidity of components used in the construction of…
A: Given data;Mass of metallic alloy = 3.826 gMass of mixture of oxides = 4.456 gThe molar mass of lead…
Q: Classify each molecule as polar or nonpolar. Electrons on the outer atoms are omitted for clarity.…
A: If the electronegativity of the covalent bond forming atoms is different then the higher…
Q: Hard water often contains dissolved Ca²+ and Mg2+ ions. One way to soften water is to add…
A: Given,Molarity of CaCl2 = 0.055 MMolarity of Mg(NO3)2 = 0.090 Mvolume of the solution = 1.0 L
Q: What substitution product will be formed from the SN2 reaction between…
A: Answer:Substitution reaction is the characteristic reaction of alkyl halide. In Sn2, S means…
Q: What orbitals are used to form the bond indicated in the following molecule? Select one: a. sp,sp O…
A: The covalent bond is formed by the overlap of the atomic orbitals between the atoms of similar…
Q: Predict the major product for the following reaction: O CH₂ NH₂ -N [H+] (-H₂O) Modify the given copy…
A: Ketone reacts with amine in acidic medium to produce imine as the product.
Q: As pure molecular solids, which of the following exhibits dipole-dipole intermolecular forces: HBr,…
A: Dipole - Dipole intermolecular forces Bond between positive end of one molecule and negative end of…
Q: Use VSEPR theory to predict the shape of (CH3)2P(O)CI. Does this molecule have a net dipole moment?…
A:
Q: For a hydrogen atom, calculate the energy of the photon that would be emitted for the orbital…
A: Data given: Initial transition, n1 = 4Final transition, n2 = 1Rydberg constant, R = 1.09678×107 m–1
Q: he reaction A → 2B was monitored as a function of time. A plot of concentration [A] ersus time…
A: The reaction rate law is the mathematical equation which relates reactant concentration along with…
Q: Four research teams measured the speed at which signals travel down a certain type of nerve fiber,…
A: Accurate measurement: Measurement which is close to the accepted or true value is referred to as…
Q: Methanol can be synthesized by combining carbon monoxide and hydrogen. CO(g) + 2H₂(g) CH3OH(g) A…
A: Le Chatelier's principle states that if an equilibrium is disturbed by changing the conditions, then…
Q: Please don't provide handwritten solution .....
A: Heat capacity of the calorimeter=7.505 J/°CExplanation:Step 1: mass of the pure copper m1 =45.90…
Q: A catalyst decreases the activation energy of a particular exothermic reaction by 33 kJ/mol, to 25…
A: Activation energy of catalyzed reaction = 25 kJ/molActivation energy difference between the…
Q: Provide the correct IUPAC name for the skeletal (line-bond) structure shown here.
A: The correct IUPAC name of the given skeletal structure given below.
Q: Draw the major product of this reaction. Ignore inorganic byproducts. FeBr3 Select to Draw Br Q
A: The question is based on organic reactions.We need to identify the product and explain its…
Q: The compound cyclohexanol, C6H₁2O, is a good fuel. It is a liquid at ordinary temperatures. When the…
A: Answer:here, ai are stoichiometric coefficients of products and reactants respectively.
Q: Part A Enter a balanced equation for the photosynthesis reaction in which gaseous carbon dioxide and…
A: In a balanced chemical equation, no. of atoms of each element are equal for both reactants and…
Q: The theoretical heat of solution of sodium nitrate, NaNO3, is 20.50 kJ/mol. When 1 mole of NaNO3 is…
A: When a reaction has negative enthalpy change, i.e , the reaction is exothermic reaction, and it…
Q: но. HO Group 1:[ Group 2:[ CH₂OH OH This is the pyranose structure of beta-D-galactose, four…
A: The objective of the question is to predict the position (equatorial and axial) of groups in…
Q: In Universe L, recently discovered by an intrepid team of chemists who also happen to have studied…
A: Answer:In an atom, there is nucleus at the centre and electrons are revolving around it. Protons are…
Q: 27. How many transition states and intermediates would the reaction profile have for the reaction…
A: Given is organic reaction.Given reaction is substitution reaction.Let's see reaction mechanism to…
Q: A student sets up and solves the following equation to solve a problem in solution stoichiometry.…
A: In this question, we need to fill the missing part of the student's equation.
Q: We're told oxygen is the most common element in the Earth's solid crust. But how much oxygen is…
A:
Q: Read the descriptions below of two substances and an experiment on each. Decide whether the result…
A:
Q: Please don't provide handwritten solution .....
A: A flying-wegde projection can be converted into Fischer by:aligning the flying wedge in the vertical…
Q: A galvanic (voltaic) cell consists of an inert platinum electrode in a solution containing 1.0 M…
A: The given cell is a voltaic cell or a galvanic cell. A galvanic cell is a cell that uses chemical…
Q: Please don't provide handwritten solution .....
A: The question is based on the concept of aromaticity.We need to explain the aromatic behaviour of…
Q: The standard emf for the cell using the overall cell reaction below is +0.48 V: Zn(s) + Ni2+ (aq) →…
A: Standard emf of cell = 0.48 VCell reaction : and [Ni2+] =0.100 M and [Zn2+] =1.50 MWe need…
Q: For the experiment this week, you'll use the relationship between FeSCN²+ absorbance and…
A: Use the equation of linear regression to calculate the concentration of the FeSCN2+ in an unknown…
Q: Q18. Convert 1.400x 10-8 liters to nanoliters and express the answer in fixed notation using the…
A: The conversion of quantity from one unit system to another unit system is known as unit conversion.…
Q: Construct an enthalpy diagram with the following data to calculate the electron affinity of bromine.…
A: Enthalpy is identified as a state function which suggests that it is additive in nature. The…
Q: There are three sets of sketches below, showing the same pure molecular compound (hydrogen chloride,…
A: In the given question we have to choose the correct options for the given boxes.The melting point of…
Q: Na2CO3(aq) +CaCl₂(aq) →2 NaCl(aq) + CaCO3(s) Calculate the volume (in mL) of 0.100 M CaCl2 needed to…
A: Let x L of CaCl2 be required then, Moles of CaCl2 required = molarity * volume in Litre = 0.100…
Q: The van der Waals equation of state was designed (by Dutch physicist Johannes van der Waals) to…
A: Note: Since you have posted a question with multiple sub parts, we will provide the solution only to…
Q: R and Senantiomers. However, if only one were present, which isomers of hydrobenzoin are potential…
A: We have to choose the correct option.
Please don't provide handwritten solution ......
Step by step
Solved in 5 steps with 5 images
- A 0.500g sample is analyzed spectrophotometrically for manganese by dissolving it in acid and transferring to a 250 mL flask and diluting to volume. Three aliquots ae analyzed by transferring 50 mL portions with a pipet to 500 mL Erlenmeyer flask and reacting with an oxidizing agent, potassium peroxydisulfate, to convert the manganese to permanganate. After reaction, these are quantitatively transferred to 250 mL volumetric flasks, diluted to volume and measured spectrophotometrically. By comparison with standards, the average concentration of the final solution is determined to be 1.25 x 10^-5M. What is the percent manganese in the sample?A student determined fluoride in a toothpaste sample using ion chromatography. A toothpaste sample of mass 0.100 g was dissolved in type I water and then quantitatively filtered through a Whatman #1 filter paper into a clean 100 ml volumetric flask. The flask was then made up to volume with type I water and mixed thoroughly.A portion of the solution was filtered through a 0.45 um filter into a sample vial for analysis. Analysis of the sample gave a fluoride concentration of 1.60 mg/l Calculate the % w/w fluoride in the original toothpaste sample. (Give your answer to 3 decimal places please)Five white, 500-mg uncoated ascorbic acid (AA) tablets with an average weight of 0.6100-g were pulverized in a mortar. A sample of the powdered ascorbic acid weighing 0.4610-g was placed in an iodine flask and was dissolved in 50-mL H2SO4 then 5-g of KBr was added to the resulting solution. The solution was titrated with 46.73-mL of 0.0152 M STD. KBrO3 to reach a faint yellow endpoint then 3-g KI and 5-mL Starch TS. The blue color solution is then titrated with 2.78-mL of 0.1047 M STD. Na2S2O3 to reach the disappearance of the blue iodostarch complex. MW: KBrO3 = 167.0 ; KIO3 = 214.0 ; Na2S2O3 = 158.11 ; C6H8O6 = 176.12 Compute the milligrams of pure AA per tablet from the assay. None of the choices 349.7 mg 264.3 mg 462.7 mg
- A 2.0 g of MgCO3 was dissolved and diluted to exactly 500-mL volumetric flask. If 50-mL aliquot was used in the analysis, what is the weight of MgCO3 present in the aliquot sampleYou are preparing a 100.0 mL standard solution needed for titration analysis. The NaOH (40 g/mol) pellets are measured to be 0.5341 g in a balance with acceptable uncertainty of +0.001 g. Mass of the pellets is recorded after taring the container. The pellets are put in a beaker and added with 50 ml distilled water measured by a graduated cylinder. The solution is then quantitatively transferred to a 100-mL volumetric flask with uncertainty of ±0.08 mL and diluted to a 100-mL mark. What is the concentration (M) of the solution and estimate its uncertainty by propagation? Assumption: There is no uncertainty in molar mass. Express your answer as C+/- u M.In the Analytical Chemistry laboratory, one of the B.Sc student Ms. Fatma wanted to analyze the presence of Iron(II) ion in the water samples collected from Sohar Industrial Area in the Sultanate of Oman and analyzed by Spectrophotometric method. (1) 250.00 mL of this water sample (Solution A) known to contain unknown amount of FeSO4. She has diluted Solution A by a dilution factor 10 to make 250.00 mL solution, which she labeled Solution B. Using Spectrophotometer, she has measured the absorbance value (0.642) for Solution B at 508 nm using 1.00 cm cell (cuvet). The molar absorptivity value for Fe2* ion at 508 nm is ɛ508 = 30.8 M-1cm1. (i) What volume of the solution A did she require to make the 250.00 mL of Solution В? (ii) in (i)? What instrument should she use to transfer the volume of the Solution A calculated (ii) Concentration of FeSO4 in Solution B. (iv) Concentration of FeSO4 in Solution A. Mass of FeSO4 in Solution A (Show your calculation) (v)
- ASSAY Calibration solutions Calibration solutions of naproxen in the range 5 – 25 μg/mL were prepared. Sample preparation 20 tablets weighing 12.3819 g were crushed to a fine powder. A portion of the powder (145.4 mg) was shaken with approximately 150 mL of acetic acid (0.05 M) for 5 min and then made up to volume in a 250 mL volumetric flask (stock solution). Approximately 50 mL of the stock solution was filtered and a 25 mL aliquot was diluted to 100 mL in a volumetric flask. 10 mL of the resulting solution was further diluted to 100 mL with acetic acid (0.05 M). Analysis The standards and sample solutions were analyzed by HPLC under the following conditions: Column: octadecylsilyl (ODS), 4.6 mmx150 mm, mobile phase: acetonitrile : 0.05 M acetic acid (85:15), flow rate: 1 ml/min, UV detection at 243 nm. Results: A calibration curve of concentration versus peak area was constructed for the standard solutions and gave the straight-line equation: y = 3555.6x + 85, r = 0.9999 The area…In a similar experiment, the mass of 3 PB tablets was measujed to be 3.1177 g. The tablets were crushed, and 2.9862 g of the powder was transferred to a beaker and reacted with HCI. After filtration, the filtrate was transferred to a 50-mL volumetric flask and diluted with water. 10.00 mL of this stock solution was combined with 0.2 M NagPO4. The resulting precipitate weighed 0.2694 g after drying. What is the mass of BSS per tablet in mg? Round your answer to 1 decimal place.A researcher reconstituted a vial of 750 mg Cefuroxime Sodium Powder for Injection with 6mL of sterile water for injection. The reconstituted solution was dark amber-colored solution. The package insert states that solution colors range from clear to yellow depending on concentration, diluent, and storage conditions. The researcher was then hesitant to give the patient the solution due to its unusual dark color. Five portions were taken from a batch of cefuroxime sodium. Prior to testing in the instrument, each part was subjected to one of the following conditions: Conditions Specifications Temperature Portion 1: 8°C ± 2°C Portion 2: 30°C ± 2°C Portion 3: 40°C ± 2°C Light Portion 4: Kept in the dark Portion 5: Exposed to direct sunlight 1. Of the several solutions prepared, which absorbance value results should be compared with each other to answer the questions of the pharmacist? Explain your answer.
- A 20.0 mL sample of commercial bleach was diluted with water to a 250.0 mL volumetric flask. A 50.0 mL aliquot of the diluted sample was treated with excess KI and starch. The liberated iodine was titrated with 0.399 M Na2S2O3, requiring 13.9 mL to reach the end point. (a) Identify the type of redox titration method used. (b) Identify the indicator and endpoint color. (c) Calculate the % w/v NaOCl in the sample.A student weighed approximately 1.5 g of an unknown solid acid and carefully placed the sample in a clean, but not necessarily dry, 250.0 mL volumetric flask. The student added deionized water to the flask, swirled the solution until the solid acid dissolved, then added sufficient deionized water to fill the flask to the fill line. A volumetric pipet was used to transfer 25.00 mL of the resulting solution to an Erlenmeyer flask, and 2 – 3 drops of phenolphthalein were added.The student filled the sodium hydroxide buret and titrated the acid solution with standardized 0.1000 M NaOH to the first permanent faint pink color, then repeated the titration a second time.Your instructor will provide the mass of unknown solid acid, as well as the initial and final buret readings for the two titrations. From this data and the information above, you will be able to calculate the molar mass of the unknown acid.The unknown solid acid is diprotic; that is, there are two moles of ionizable H+ ions per…A student weighed approximately 1.5 g of an unknown solid acid and carefully placed the sample in a clean, but not necessarily dry, 250.0 mL volumetric flask. The student added deionized water to the flask, swirled the solution until the solid acid dissolved, then added sufficient deionized water to fill the flask to the fill line. A volumetric pipet was used to transfer 25.00 mL of the resulting solution to an Erlenmeyer flask, and 2 – 3 drops of phenolphthalein were added.The student filled the sodium hydroxide buret and titrated the acid solution with standardized 0.1000 M NaOH to the first permanent faint pink color, then repeated the titration a second time.Your instructor will provide the mass of unknown solid acid, as well as the initial and final buret readings for the two titrations. From this data and the information above, you will be able to calculate the molar mass of the unknown acid.The unknown solid acid is diprotic; that is, there are two moles of ionizable H+ ions per…