A 0.5892 g of an Acetylsalicylic Acid (a monoprotic acid, FW 192.14) sample was titrated with a 0.1273 M standard NaOH solution. The titration data is given. V' (mL) ApH/AV V (mL) 0.00 6.25 7.18 10.11 12.32 13.32 13.55 13.78 14.01 14.24 14.47 14.70 14.90 15.84 16.87 17.83 18.86 pH 2.79 3.64 3.82 4.23 4.54 4.98 5.01 5.18 5.41 5.96 9.93 10.47 10.66 11.11 11.38 11.43 11.50 3.13 6.72 8.65 11.22 12.82 13.44 13.67 13.90 14.13 14.36 14.59 14.80 15.37 16.36 17.35 18.35 0.14 0.19 0.14 0.14 0.44 0.13 0.74 1.00 2.39 17.26 2.35 0.95 0.48 0.26 0.05 0.07 V" (mL) 4.92 7.68 9.93 12.02 13.13 13.55 13.78 14.01 14.24 14.47 14.69 15.09 15.86 16.85 17.85 A²pH/AV¹2 0.02 -0.03 0.00 0.19 -0.50 2.65 1.13 6.05 64.65 -64.84 -6.50 -0.83 -0.22 -0.21 0.02

Chemistry: The Molecular Science
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Chapter15: Additional Aqueous Equilibria
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From the data, give 3 potentiometric plots. Show the equivalence point in the 3 graphs.

A 0.5892 g of an Acetylsalicylic Acid (a monoprotic acid, FW 192.14) sample was titrated with a
0.1273 M standard NaOH solution. The titration data is given.
V' (ml)
ApH/AV
V (mL)
0.00
6.25
7.18
10.11
12.32
13.32
13.55
13.78
14.01
14.24
14.47
14.70
14.90
15.84
16.87
17.83
18.86
pH
2.79
3.64
3.82
4.23
4.54
4.98
5.01
5.18
5.41
5.96
9.93
10.47
10.66
11.11
11.38
11.43
11.50
3.13
6.72
8.65
11.22
12.82
13.44
13.67
13.90
14.13
14.36
14.59
14.80
15.37
16.36
17.35
18.35
0.14
0.19
0.14
0.14
0.44
0.13
0.74
1.00
2.39
17.26
2.35
0.95
0.48
0.26
0.05
0.07
V" (mL)
4.92
7.68
9.93
12.02
13.13
13.55
13.78
14.01
14.24
14.47
14.69
15.09
15.86
16.85
17.85
A²pH/AV¹2
0.02
-0.03
0.00
0.19
-0.50
2.65
1.13
6.05
64.65
-64.84
-6.50
-0.83
-0.22
-0.21
0.02
Transcribed Image Text:A 0.5892 g of an Acetylsalicylic Acid (a monoprotic acid, FW 192.14) sample was titrated with a 0.1273 M standard NaOH solution. The titration data is given. V' (ml) ApH/AV V (mL) 0.00 6.25 7.18 10.11 12.32 13.32 13.55 13.78 14.01 14.24 14.47 14.70 14.90 15.84 16.87 17.83 18.86 pH 2.79 3.64 3.82 4.23 4.54 4.98 5.01 5.18 5.41 5.96 9.93 10.47 10.66 11.11 11.38 11.43 11.50 3.13 6.72 8.65 11.22 12.82 13.44 13.67 13.90 14.13 14.36 14.59 14.80 15.37 16.36 17.35 18.35 0.14 0.19 0.14 0.14 0.44 0.13 0.74 1.00 2.39 17.26 2.35 0.95 0.48 0.26 0.05 0.07 V" (mL) 4.92 7.68 9.93 12.02 13.13 13.55 13.78 14.01 14.24 14.47 14.69 15.09 15.86 16.85 17.85 A²pH/AV¹2 0.02 -0.03 0.00 0.19 -0.50 2.65 1.13 6.05 64.65 -64.84 -6.50 -0.83 -0.22 -0.21 0.02
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