9.18 An aqueous solution of furfural contains 4 mol % furfural. It is to be continuously fractionaled at 1 std atm pressure to provide solutions containing 0.1 and 99.5 mol % furfural, respectively. Feed is liquid at the bubble point. Equilibrium data ("The Chemical Engineers' Handbook," 4th ed., p. 13-5), x, y = mole fraction furfural: 1, °C y* 1, °C y* 100. 100.6 0.80 0.11 0 10

Introduction to Chemical Engineering Thermodynamics
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9.18 An aqueous solution of furfural contains 4 mol % furfural. It is to be continuously fractionated
at 1 std atm pressure to provide solutions containing 0.1 and 99.5 mol % furfural, respectively. Feed
is liquid at the bubble point. Equilibrium data ("The Chemical Engineers' Handbook," 4th ed., p.
13-5), x, y mole fraction furfural:
1, °C
y*
1, °C
y*
100.6
0.80
0.11
100.
98.56
0.19
0.32
0.64
109.5
0.90
0.055
0.080
0.01
122.5
146.0
154.8
0.92
0.94
0.96
0.98
98.07
0.02
97.90
97.90
0.092
0.092
0.04
0.092
0.81
97.90
0.50
0.092
158.8
0.90
98.7
0.70
0.095
161.7
1.00
1.00
(a) Arrange a scheme for the separation using kettle-type reboilers, and determine the number
of theoretical trays required for a vapor boilup rate of 1.25 times the minimum for an infinite
number of trays.
(b) Repeat part (a) but use open steam at essentially atmospheric pressure for the tower
delivering the water-rich product, with 1.25 times the minimum steam and vapor boilup rates.
(c) Which scheme incurs the greater furfural loss to the water-rich product?
Transcribed Image Text:9.18 An aqueous solution of furfural contains 4 mol % furfural. It is to be continuously fractionated at 1 std atm pressure to provide solutions containing 0.1 and 99.5 mol % furfural, respectively. Feed is liquid at the bubble point. Equilibrium data ("The Chemical Engineers' Handbook," 4th ed., p. 13-5), x, y mole fraction furfural: 1, °C y* 1, °C y* 100.6 0.80 0.11 100. 98.56 0.19 0.32 0.64 109.5 0.90 0.055 0.080 0.01 122.5 146.0 154.8 0.92 0.94 0.96 0.98 98.07 0.02 97.90 97.90 0.092 0.092 0.04 0.092 0.81 97.90 0.50 0.092 158.8 0.90 98.7 0.70 0.095 161.7 1.00 1.00 (a) Arrange a scheme for the separation using kettle-type reboilers, and determine the number of theoretical trays required for a vapor boilup rate of 1.25 times the minimum for an infinite number of trays. (b) Repeat part (a) but use open steam at essentially atmospheric pressure for the tower delivering the water-rich product, with 1.25 times the minimum steam and vapor boilup rates. (c) Which scheme incurs the greater furfural loss to the water-rich product?
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