9. Write structural formulas for the major organic product(s) for the following reactions. Be sure to indicate stereochemistry when relevant. (CH;CH,CH,),CuLi `CI Br PdL2 (b) .B НО CH;CH,CH,CH,OH C,H;MgBr

Organic Chemistry
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ISBN:9781305080485
Author:John E. McMurry
Publisher:John E. McMurry
Chapter10: Organohalides
Section10.SE: Something Extra
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9.
Write structural formulas for the major organic product(s) for the following reactions. Be sure to
indicate stereochemistry when relevant.
(CH;CH,CH,),CuLi
(a)
Cl
Br
PAL2
(b)
HO
(c)
CH;CH,CH,CH,OH
C,H5MgBr
10.
Propose a reasonable mechanism for the following reaction Be sure to include all intermediates.
(transition states are not necessary)
Br
Br
hv
CH3-CH=C(CH3)2 +
Br,
ČH,-CH=C(CH3)2
CH2=CH–Ċ(CH3)2
11.
Indicate how each of the following compounds could be prepared using the given starting
material
CH;CH,CH,CH3
CH;CH,CH,CH,Br
CH;CH,CH,CH3
H,C=CH-CH=CH2
Br
CH;CHCH,CH3
CH;CH=CCH,CH3
CH3
Transcribed Image Text:9. Write structural formulas for the major organic product(s) for the following reactions. Be sure to indicate stereochemistry when relevant. (CH;CH,CH,),CuLi (a) Cl Br PAL2 (b) HO (c) CH;CH,CH,CH,OH C,H5MgBr 10. Propose a reasonable mechanism for the following reaction Be sure to include all intermediates. (transition states are not necessary) Br Br hv CH3-CH=C(CH3)2 + Br, ČH,-CH=C(CH3)2 CH2=CH–Ċ(CH3)2 11. Indicate how each of the following compounds could be prepared using the given starting material CH;CH,CH,CH3 CH;CH,CH,CH,Br CH;CH,CH,CH3 H,C=CH-CH=CH2 Br CH;CHCH,CH3 CH;CH=CCH,CH3 CH3
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