Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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![**Question 9:** Which of the following compounds has an S configuration?
**Compound A:**
- Structure: A chiral center with a central carbon.
- Substituents: Methyl (CH₃), ethyl (C₂H₅), hydrogen (H), and hydroxyl group (OH).
**Compound B:**
- Structure: A chiral center with a central carbon.
- Substituents: Bromine (Br), hydrogen (H), chlorine (Cl), and methyl (CH₃).
**Compound C:**
- Structure: A chiral center with a central carbon.
- Substituents: Bromine (Br), a propyl group (CH₂CH₂CH₃), two methyl groups (CH₃).
**Compound D:**
- Structure: A chiral center with a central carbon.
- Substituents: Chlorine (Cl), hydrogen (H), methyl (CH₃), hydrogen (H).
Each compound contains a chiral center with various substituents that determine its configuration as either R or S according to Cahn-Ingold-Prelog priority rules. To identify the S configuration, the priorities of the substituents must be determined based on atomic number and connectivity. Visual cues, such as solid and dashed wedges, indicate the spatial arrangement needed to apply the R/S rules.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F63e2e494-b56f-474b-94e6-a1b0d865891f%2F632c1039-6113-4686-9a1b-f1328394c719%2Fia99gr_processed.jpeg&w=3840&q=75)
Transcribed Image Text:**Question 9:** Which of the following compounds has an S configuration?
**Compound A:**
- Structure: A chiral center with a central carbon.
- Substituents: Methyl (CH₃), ethyl (C₂H₅), hydrogen (H), and hydroxyl group (OH).
**Compound B:**
- Structure: A chiral center with a central carbon.
- Substituents: Bromine (Br), hydrogen (H), chlorine (Cl), and methyl (CH₃).
**Compound C:**
- Structure: A chiral center with a central carbon.
- Substituents: Bromine (Br), a propyl group (CH₂CH₂CH₃), two methyl groups (CH₃).
**Compound D:**
- Structure: A chiral center with a central carbon.
- Substituents: Chlorine (Cl), hydrogen (H), methyl (CH₃), hydrogen (H).
Each compound contains a chiral center with various substituents that determine its configuration as either R or S according to Cahn-Ingold-Prelog priority rules. To identify the S configuration, the priorities of the substituents must be determined based on atomic number and connectivity. Visual cues, such as solid and dashed wedges, indicate the spatial arrangement needed to apply the R/S rules.
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