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8.22 The volume of a binary mixture has been reported in the following polynomial form: V(T.P.₁.2) = xb₁ + ₂b + 12 (21-22)' inl) a. What values should be used for b, and by? b. Derive, from the equation here, expressions for V V₂, V = V₁-V, and V-V₂-V₂. c. Derive, from the equation here, expressions for the partial molar excess volumes of each species at infinite dilution, that is, (T. P.₁ 0) and V (T.P.2₂-0). 1

8.22 The volume of a binary mixture has been reported in the following polynomial form: V(T.P.₁.2) = xb₁ + ₂b + 12 (21-22)' inl) a. What values should be used for b, and by? b. Derive, from the equation here, expressions for V V₂, V = V₁-V, and V-V₂-V₂. c. Derive, from the equation here, expressions for the partial molar excess volumes of each species at infinite dilution, that is, (T. P.₁ 0) and V (T.P.2₂-0). 1

Introduction to Chemical Engineering Thermodynamics
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
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8.22 The volume of a binary mixture has been reported in the following polynomial form: V(T.P.1₁.x) = x₁b₁ + 1₂b₂ + 1x₂ [₁(21-22)' a. What values should be used for by and by? b. Derive, from the equation here, expressions for V V₂, V = V₁-V, and V=V₂-V₂. c. Derive, from the equation here, expressions for the partial molar excess volumes of each species at infinite dilution, that is, (T. P., →0) and V (T. P. 2₂-0).
Transcribed Image Text:8.22 The volume of a binary mixture has been reported in the following polynomial form: V(T.P.1₁.x) = x₁b₁ + 1₂b₂ + 1x₂ [₁(21-22)' a. What values should be used for by and by? b. Derive, from the equation here, expressions for V V₂, V = V₁-V, and V=V₂-V₂. c. Derive, from the equation here, expressions for the partial molar excess volumes of each species at infinite dilution, that is, (T. P., →0) and V (T. P. 2₂-0).
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