8. The reaction below represents the decomposition of a generic diatomic molecule in its standard state. /2 A2(g) → A(g)

Chemistry & Chemical Reactivity
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Author:John C. Kotz, Paul M. Treichel, John Townsend, David Treichel
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Chapter18: Principles Of Chemical Reactivity: Entropy And Free Energy
Section18.7: The Interplay Of Kinetics And Thermodynamics
Problem 2.2ACP: It has been demonstrated that buckminsterfullerene (C60), another allotrope of carbon (Section 2.3),...
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18. The reaction below represents the
decomposition of a generic diatomic
molecule in its standard state.
1/2 A2(g) → A(g)
Assuming that the standard molar Gibbs
energy of formation of A(g) is 8.12 kJ•mol–1
at 2500 K and -72.20 kJ•mol-1 at 3500 K.
Calculate the value of K (thermodynamic
equilibrium constant) at each temperature.
Determine the value of AH°rxn for these
data assuming that AH°rxn is independent
of temperature.
Transcribed Image Text:18. The reaction below represents the decomposition of a generic diatomic molecule in its standard state. 1/2 A2(g) → A(g) Assuming that the standard molar Gibbs energy of formation of A(g) is 8.12 kJ•mol–1 at 2500 K and -72.20 kJ•mol-1 at 3500 K. Calculate the value of K (thermodynamic equilibrium constant) at each temperature. Determine the value of AH°rxn for these data assuming that AH°rxn is independent of temperature.
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