8. Hooke's law in wavenumbers is V = 1 2TC H with c as speed of light in cm/s, f in dyn/cm, u in g. The force constant for a C-O bond is 5.0 x 105 dyn/cm, and for an 0-0 bond is 3.8 x 105 dyn/cm. (a) Which stretch (C-O or 0-0) would be observed at a higher wavenumber? (b) calculate the wave number for the C-O and O-O stretches in di-t-butylperoxide. (Note: be sure to convert to g per atom from g/mol.
8. Hooke's law in wavenumbers is V = 1 2TC H with c as speed of light in cm/s, f in dyn/cm, u in g. The force constant for a C-O bond is 5.0 x 105 dyn/cm, and for an 0-0 bond is 3.8 x 105 dyn/cm. (a) Which stretch (C-O or 0-0) would be observed at a higher wavenumber? (b) calculate the wave number for the C-O and O-O stretches in di-t-butylperoxide. (Note: be sure to convert to g per atom from g/mol.
Chemistry
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ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Hooke's Law and Spectroscopy
![8. Hooke's law in wavenumbers is
f
店
V = 2πε μ
with c as speed of light in cm/s, f in dyn/cm, u in g.
The force constant for a C-O bond is 5.0 x 105 dyn/cm, and for an O-O bond is 3.8 x 105 dyn/cm.
(a) Which stretch (C-O or 0-0) would be observed at a higher wavenumber?
(b) calculate the wave number for the C-O and O-O stretches in di-t-butylperoxide. (Note: be sure to convert to g
per atom from g/mol.](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2Fdb688f85-aacf-4966-891c-9ccccc50e8d7%2Ff6d08fd2-24a8-4029-aa38-d4ae9e7f6de7%2Fs92p05l_processed.jpeg&w=3840&q=75)
Transcribed Image Text:8. Hooke's law in wavenumbers is
f
店
V = 2πε μ
with c as speed of light in cm/s, f in dyn/cm, u in g.
The force constant for a C-O bond is 5.0 x 105 dyn/cm, and for an O-O bond is 3.8 x 105 dyn/cm.
(a) Which stretch (C-O or 0-0) would be observed at a higher wavenumber?
(b) calculate the wave number for the C-O and O-O stretches in di-t-butylperoxide. (Note: be sure to convert to g
per atom from g/mol.
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