8. A 50.0 g sample of water at 70.0 °C is mixed with 60.0 g of water at 20.0 °C. Find the final temperature of the mixture if no heat is transferred to or from the container or surroundings.
Thermochemistry
Thermochemistry can be considered as a branch of thermodynamics that deals with the connections between warmth, work, and various types of energy, formed because of different synthetic and actual cycles. Thermochemistry describes the energy changes that occur as a result of reactions or chemical changes in a substance.
Exergonic Reaction
The term exergonic is derived from the Greek word in which ‘ergon’ means work and exergonic means ‘work outside’. Exergonic reactions releases work energy. Exergonic reactions are different from exothermic reactions, the one that releases only heat energy during the course of the reaction. So, exothermic reaction is one type of exergonic reaction. Exergonic reaction releases work energy in different forms like heat, light or sound. For example, a glow stick releases light making that an exergonic reaction and not an exothermic reaction since no heat is released. Even endothermic reactions at very high temperature are exergonic.
 alt="8. A 50.0 g sample of water at 70.0 °C is mixed with 60.0 g of water at 20.0 °C. Find the final
temperature of the mixture if no heat is transferred to or from the container or
surroundings.
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9. The molar heat of solution of a substance is found to be +21.38 kJ/mol. The addition of
0.100 mol of this substance to 1.000 L of water initially at 40.0 °C results in a temperature
decrease. Assume the specific heat of the resulting solution to be equal to that of pure
water. Find the final temperature of the solution (Also assume that the heat capacity of the
calorimeter is negligible.)
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10. A student using a calibrated solution calorimeter measured a temperature decrease of
1.10 K when 1.00 g of KNO3 was added to 74.40 g of deionized water in the calorimeter. The
specific heat capacity of the solution calorimeter was found to be 4.15 J/g•K. Calculate the
experimental value of the molar heat of solution of KNO3, AHsoln. Was the dissolution of this
salt exothermic or endothermic?
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