75. The reaction of CO with Cl₂ gives phosgene (COCl₂), a nerve gas that was used in World War I. Use the mechanism shown here to complete the following exercises: Cl₂(g) = 2Cl(g) (fast, k₁ represents the forward rate constant, k_₁ the reverse rate constant) COCI(g) (slow, k₂ the rate constant) CO(g) + Cl(g) COCI(g) + Cl(g) -> COC12(g) (fast, k3 the rate constant) (a) Write the overall reaction. (b) Identify all intermediates. (c) Write the rate law for each elementary reaction. (d) Write the overall rate law expression. -

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Chapter1: Chemical Foundations
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75. The reaction of CO with Cl₂ gives phosgene (COCI₂), a nerve gas that was used in World War I. Use the
mechanism shown here to complete the following exercises:
Cl₂(g) = 2Cl(g) (fast, k₁ represents the forward rate constant, k_₁ the reverse rate constant)
CO(g) + Cl(g)
COCI(g) (slow, k₂ the rate constant)
COCI(g) + Cl(g) -> COC12(g) (fast, k3 the rate constant)
(a) Write the overall reaction.
(b) Identify all intermediates.
(c) Write the rate law for each elementary reaction.
(d) Write the overall rate law expression.
Transcribed Image Text:75. The reaction of CO with Cl₂ gives phosgene (COCI₂), a nerve gas that was used in World War I. Use the mechanism shown here to complete the following exercises: Cl₂(g) = 2Cl(g) (fast, k₁ represents the forward rate constant, k_₁ the reverse rate constant) CO(g) + Cl(g) COCI(g) (slow, k₂ the rate constant) COCI(g) + Cl(g) -> COC12(g) (fast, k3 the rate constant) (a) Write the overall reaction. (b) Identify all intermediates. (c) Write the rate law for each elementary reaction. (d) Write the overall rate law expression.
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