729 Identify the relationship in each of the following pairs. Do the drawings represent consti- tutional isomers or tereoisomers, or are they just different ways of drawing the same compound? If they are stereoisomers, are they enantiomers or diastereomers? (Molecular models may prove useful in this problem.) H CH, (a) CH,Br and -CH,OH HO Br CH, Br (b) c-CH, CH,CH, C-Br and CH,CH, CH, Hc H (c) Br and -CH,CH, CH,CH, Br

Organic Chemistry
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Author:William H. Brown, Brent L. Iverson, Eric Anslyn, Christopher S. Foote
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Chapter23: Amines
Section: Chapter Questions
Problem 23.22P
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129 Identify the relationship in each of the following pairs. Do the drawings represent consti-
tutional isomers or stereoisomers, or are they just different ways of drawing the same compound?
Ir they are stereoisomers, are they enantiomers or diastereomers? (Molecular models may prove
useful in this problem.)
CH)
(a)
C-CH,Br and
c-CH,OH
HO
Br
CH,
H.
Br
H,
(b)
C-Br
and
CH,
CH,CH,
CH,CH,
CH,
Hc H
C-CH,CH,
(c)
C-Br
and
CH,CH,
Br
CH,
and
Br
CH,CH,
CH,OH
CH,OH
(e) HOH
ČHOH
and
но-
ČH,OH
H,C
(r)
and
For Problem No. 7.29 (a) to (f), IDENTIFY the given pair of structures
as described below and WRITE:
EN if the pair represents ENANTIOMERS
DI if the pair represents DIASTEREOMERS
co if the pair represents CONSTITUTIONAL isomers
ID if the two molecules represent IDENTICAL compounds
Transcribed Image Text:129 Identify the relationship in each of the following pairs. Do the drawings represent consti- tutional isomers or stereoisomers, or are they just different ways of drawing the same compound? Ir they are stereoisomers, are they enantiomers or diastereomers? (Molecular models may prove useful in this problem.) CH) (a) C-CH,Br and c-CH,OH HO Br CH, H. Br H, (b) C-Br and CH, CH,CH, CH,CH, CH, Hc H C-CH,CH, (c) C-Br and CH,CH, Br CH, and Br CH,CH, CH,OH CH,OH (e) HOH ČHOH and но- ČH,OH H,C (r) and For Problem No. 7.29 (a) to (f), IDENTIFY the given pair of structures as described below and WRITE: EN if the pair represents ENANTIOMERS DI if the pair represents DIASTEREOMERS co if the pair represents CONSTITUTIONAL isomers ID if the two molecules represent IDENTICAL compounds
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