7:23 a.m. Mon 29 Jan Problem • Chloromethane reacts with dilute sodium cyanide (Na+ ¯C=N) according to the following equation: H3C-CI chloromethane + CEN cyanide Problem • The reaction of tert-butyl chloride with methanol CH3 H3C-C-CI CH3 tert-butyl chloride . When the concentration of chloromethane is doubled, the rate is observed to double. + H3C-OH H3C-C=N acetonitrile When the concentration of cyanide ion is tripled, the rate is observed to triple. (a) What is the kinetic order with respect to chloromethane? (b) What is the kinetic order with respect to cyanide ion? (c) What is the kinetic order overall? (d) Write the rate equation for this reaction. v = kr.[CH3C1].[CN-] methanol is found to follow the rate equation 76% C CH3 H3C-C-OCH 3 CH3 methyl tert-butyl ether + CI v = kr[(CH3)3C-C1] (a) What is the kinetic order with respect to tert-butyl chloride? (b) What is the kinetic order with respect to methanol? (c) What is the kinetic order overall? chloride + HCI

7:23 a.m. Mon 29 Jan Problem • Chloromethane reacts with dilute sodium cyanide (Na+ ¯C=N) according to the following equation: H3C-CI chloromethane + CEN cyanide Problem • The reaction of tert-butyl chloride with methanol CH3 H3C-C-CI CH3 tert-butyl chloride . When the concentration of chloromethane is doubled, the rate is observed to double. + H3C-OH H3C-C=N acetonitrile When the concentration of cyanide ion is tripled, the rate is observed to triple. (a) What is the kinetic order with respect to chloromethane? (b) What is the kinetic order with respect to cyanide ion? (c) What is the kinetic order overall? (d) Write the rate equation for this reaction. v = kr.[CH3C1].[CN-] methanol is found to follow the rate equation 76% C CH3 H3C-C-OCH 3 CH3 methyl tert-butyl ether + CI v = kr[(CH3)3C-C1] (a) What is the kinetic order with respect to tert-butyl chloride? (b) What is the kinetic order with respect to methanol? (c) What is the kinetic order overall? chloride + HCI

Organic Chemistry

9th Edition

ISBN:9781305080485

Author:John E. McMurry

Publisher:John E. McMurry

Chapter27: Biomolecules: Lipids

Section27.SE: Something Extra

Problem 47AP: Cembrene, C20H32, is a diterpenoid hydrocarbon isolated from pine resin. Cembrene has a UV...

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