7. Why does addition product B predominate at the higher temperature (100°℃)? A. The reaction is equilibrium controlled: product B is more stable than product A, so product B predominates. B. The reaction is kinetically controlled: product B forms faster, so product B predominates. C. Product B predominates because it has more electron delocalization than product A. D. Product B is less sterically hindered, so it predominates.

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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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Question 7
Questions 6 and 7 are based on the following reaction of 1,3-
butadiene with HCl at different
temperatures:
CH₂=CH-CH=CH₂
HCI
CH,=CH–CH–CH3
A
CH₂
-CH=CH-CH3
B
At 0°C, the following product composition is observed: product A
(80%), product B (20%). At 100°C, the following product
composition is observed: product A (25%), product B (75%).
6. Why does addition product A predominate at the lower
temperature (0°C)?
A. The reaction is equilibrium controlled: product A is more
stable than product B, so
product A predominates.
B. The reaction is kinetically controlled: product A forms faster,
so product A predominates.
C. Product A predominates because it has more [] electron
delocalization than product B.
D. Product A is less sterically hindered, so it predominates.
Transcribed Image Text:Questions 6 and 7 are based on the following reaction of 1,3- butadiene with HCl at different temperatures: CH₂=CH-CH=CH₂ HCI CH,=CH–CH–CH3 A CH₂ -CH=CH-CH3 B At 0°C, the following product composition is observed: product A (80%), product B (20%). At 100°C, the following product composition is observed: product A (25%), product B (75%). 6. Why does addition product A predominate at the lower temperature (0°C)? A. The reaction is equilibrium controlled: product A is more stable than product B, so product A predominates. B. The reaction is kinetically controlled: product A forms faster, so product A predominates. C. Product A predominates because it has more [] electron delocalization than product B. D. Product A is less sterically hindered, so it predominates.
CH₂=CH-CH=CH₂
HCI
CH2=CH—CH—CH3
-CH-
A
+
CH,—CH=CH—CH3
At 0°C, the following product composition is observed: product A
(80%), product B (20%). At 100°C, the following product
composition is observed: product A (25%), product B (75%).
6. Why does addition product A predominate at the lower
temperature (0°C)?
B
A. The reaction is equilibrium controlled: product A is more
stable than product B, so
product A predominates.
B. The reaction is kinetically controlled: product A forms faster,
so product A predominates.
C. Product A predominates because it has more electron
delocalization than product B.
D. Product A is less sterically hindered, so it predominates.
7. Why does addition product B predominate at the higher
temperature (100°C)?
A. The reaction is equilibrium controlled: product B is more
stable than product A, so
product B predominates.
B. The reaction is kinetically controlled: product B forms faster,
so product B predominates.
C. Product B predominates because it has more electron
delocalization than product A.
D. Product B is less sterically hindered, so it predominates.
Transcribed Image Text:CH₂=CH-CH=CH₂ HCI CH2=CH—CH—CH3 -CH- A + CH,—CH=CH—CH3 At 0°C, the following product composition is observed: product A (80%), product B (20%). At 100°C, the following product composition is observed: product A (25%), product B (75%). 6. Why does addition product A predominate at the lower temperature (0°C)? B A. The reaction is equilibrium controlled: product A is more stable than product B, so product A predominates. B. The reaction is kinetically controlled: product A forms faster, so product A predominates. C. Product A predominates because it has more electron delocalization than product B. D. Product A is less sterically hindered, so it predominates. 7. Why does addition product B predominate at the higher temperature (100°C)? A. The reaction is equilibrium controlled: product B is more stable than product A, so product B predominates. B. The reaction is kinetically controlled: product B forms faster, so product B predominates. C. Product B predominates because it has more electron delocalization than product A. D. Product B is less sterically hindered, so it predominates.
Expert Solution
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The question is based on the concept of organic reactions.

we need to describe the product formation at different temperature since product formation depends on temperature.

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