67, 1774 (1945)]. Calculate the initial ternary copolymer composition to compare with the composition obtained by the analysis. [Reactivity ratios: S/MMA: r 0.52, r2 = 0.46; St/VC:r = 1.8, 2 = 0.087; MMA/VC: = 2.4, r2 = 0.36.] %3D %3D %3D
67, 1774 (1945)]. Calculate the initial ternary copolymer composition to compare with the composition obtained by the analysis. [Reactivity ratios: S/MMA: r 0.52, r2 = 0.46; St/VC:r = 1.8, 2 = 0.087; MMA/VC: = 2.4, r2 = 0.36.] %3D %3D %3D
Introduction to Chemical Engineering Thermodynamics
8th Edition
ISBN:9781259696527
Author:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Chapter1: Introduction
Section: Chapter Questions
Problem 1.1P
Related questions
Question
![7.12 The ternary copolymerization of a monomer mixture containing 31.24, 31.12, and
37.64 mol% of styrene(St), methyl methacrylate(MMA), and vinylidene chloride(VC)
at 60°C for 16 h yielded at 18.2 wt% conversion a polymeric product which analyzed
C 68.66% and C? 12.07% (by wt) [C. Walling and E. R. Briggs, J. Am. Chem. Soc.,
67, 1774 (1945)]. Calculate the initial ternary copolymer composition to compare
with the composition obtained by the analysis. [Reactivity ratios: St/MMA: r =
0.52, r2 0.46; St/VC:r = 1.8, r2 = 0.087; MMA/VC: r = 2.4, r2 = 0.36.]
%3D
%3D
%3D
Ans.
Terpolymer composition (mol%)
Calcd. [Eq. (7.65)]
Feed
Calcd. [Eq. (7.66)]
Mol%
31.24
Monomer
Found
St
43.4
44.3
44.3
MMA
31.12
39.4
41.2
42.7
VC
37.64
17.2
14.5
13.0](/v2/_next/image?url=https%3A%2F%2Fcontent.bartleby.com%2Fqna-images%2Fquestion%2F658440bc-062c-437f-836c-a21782d8ce81%2F5a3b08a4-e380-4fc6-956c-bc1bb138e77a%2F2wlm2w_processed.jpeg&w=3840&q=75)
Transcribed Image Text:7.12 The ternary copolymerization of a monomer mixture containing 31.24, 31.12, and
37.64 mol% of styrene(St), methyl methacrylate(MMA), and vinylidene chloride(VC)
at 60°C for 16 h yielded at 18.2 wt% conversion a polymeric product which analyzed
C 68.66% and C? 12.07% (by wt) [C. Walling and E. R. Briggs, J. Am. Chem. Soc.,
67, 1774 (1945)]. Calculate the initial ternary copolymer composition to compare
with the composition obtained by the analysis. [Reactivity ratios: St/MMA: r =
0.52, r2 0.46; St/VC:r = 1.8, r2 = 0.087; MMA/VC: r = 2.4, r2 = 0.36.]
%3D
%3D
%3D
Ans.
Terpolymer composition (mol%)
Calcd. [Eq. (7.65)]
Feed
Calcd. [Eq. (7.66)]
Mol%
31.24
Monomer
Found
St
43.4
44.3
44.3
MMA
31.12
39.4
41.2
42.7
VC
37.64
17.2
14.5
13.0
Expert Solution
This question has been solved!
Explore an expertly crafted, step-by-step solution for a thorough understanding of key concepts.
Step by step
Solved in 2 steps with 4 images
Knowledge Booster
Learn more about
Need a deep-dive on the concept behind this application? Look no further. Learn more about this topic, chemical-engineering and related others by exploring similar questions and additional content below.Recommended textbooks for you
Introduction to Chemical Engineering Thermodynami…
Chemical Engineering
ISBN:
9781259696527
Author:
J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:
McGraw-Hill Education
Elementary Principles of Chemical Processes, Bind…
Chemical Engineering
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
Elements of Chemical Reaction Engineering (5th Ed…
Chemical Engineering
ISBN:
9780133887518
Author:
H. Scott Fogler
Publisher:
Prentice Hall
Introduction to Chemical Engineering Thermodynami…
Chemical Engineering
ISBN:
9781259696527
Author:
J.M. Smith Termodinamica en ingenieria quimica, Hendrick C Van Ness, Michael Abbott, Mark Swihart
Publisher:
McGraw-Hill Education
Elementary Principles of Chemical Processes, Bind…
Chemical Engineering
ISBN:
9781118431221
Author:
Richard M. Felder, Ronald W. Rousseau, Lisa G. Bullard
Publisher:
WILEY
Elements of Chemical Reaction Engineering (5th Ed…
Chemical Engineering
ISBN:
9780133887518
Author:
H. Scott Fogler
Publisher:
Prentice Hall
Industrial Plastics: Theory and Applications
Chemical Engineering
ISBN:
9781285061238
Author:
Lokensgard, Erik
Publisher:
Delmar Cengage Learning
Unit Operations of Chemical Engineering
Chemical Engineering
ISBN:
9780072848236
Author:
Warren McCabe, Julian C. Smith, Peter Harriott
Publisher:
McGraw-Hill Companies, The