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6.58 The common lead-acid car battery produces a large burst of current, even at low temperatures, and is rechargeable. The reac- tion that occurs while recharging a "dead" battery is 2PBSO,(s) + 2H,0(1) (a) Use AH values from Appendix B to calculate AHn (b) Use the following equations to check your answer to part (a): Pb(s) + PbO,(s) + 2H,SO,(I) (1) Pb(s) + Pb02(s) + 2SO3(g) 2PBSO,(s) AHn = -768 kJ ΔΗ rxn (2) SO3(8) + H,0(1) H,SO,(1) -132 kJ rxn

6.58 The common lead-acid car battery produces a large burst of current, even at low temperatures, and is rechargeable. The reac- tion that occurs while recharging a "dead" battery is 2PBSO,(s) + 2H,0(1) (a) Use AH values from Appendix B to calculate AHn (b) Use the following equations to check your answer to part (a): Pb(s) + PbO,(s) + 2H,SO,(I) (1) Pb(s) + Pb02(s) + 2SO3(g) 2PBSO,(s) AHn = -768 kJ ΔΗ rxn (2) SO3(8) + H,0(1) H,SO,(1) -132 kJ rxn

Chemistry
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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6.58 The common lead-acid car battery produces a large burst of current, even at low temperatures, and is rechargeable. The reac- tion that occurs while recharging a "dead" battery is 2PBSO,(s) + 2H,0(1) (a) Use AH values from Appendix B to calculate AHn: (b) Use the following equations to check your answer to part (a): Pb(s) + PbO,(s) + 2H,SO,(1) (1) Pb(s) + PbO2(s) + 2SO3(g) .2PBSO,(s) -768 kJ rxn (2) SO,(g) + H,O(1) H,SO,(I) AH = - 132kJ AAAMA rxn
Transcribed Image Text:6.58 The common lead-acid car battery produces a large burst of current, even at low temperatures, and is rechargeable. The reac- tion that occurs while recharging a "dead" battery is 2PBSO,(s) + 2H,0(1) (a) Use AH values from Appendix B to calculate AHn: (b) Use the following equations to check your answer to part (a): Pb(s) + PbO,(s) + 2H,SO,(1) (1) Pb(s) + PbO2(s) + 2SO3(g) .2PBSO,(s) -768 kJ rxn (2) SO,(g) + H,O(1) H,SO,(I) AH = - 132kJ AAAMA rxn
Appendix B Standard Thermodynamic Values for Selected Substances* ΔΗ (kJ/mol) AG (kJ/mol) S° Substance AH? (kJ/mol) AG (kJ/mol) or lon (J/mol-K) Substance or lon (J/mol-K) 10 CaCO,(s) IS CaO(s) Dr Ca(OH)2(s) Ca3(PO4)2(s) CASO4(s) 20.87 -1206.9 -1128.8 92.9 -603.5 -898.56 -3899 - 1320.3 38.2 83.39 263 -635.1 e (g) -986.09 -4138 Aluminum e 28.3 -481.2 -313 -628.9 Al(s) Al"(ag) AICI(s) Al>Os(s) Barium Ba(s) -524.7 107 -1432.7 110.7 50.94 Carbon -704.2 -1676 -1582 5.686 2.439 158.0 C(graphite) 0. 2.866 1.896 715.0 -110.5 -393.5 -412.9 -676.26 -691.11 -698.7 62.5 O C(diamond) 669.6 144.8 170.28 C(g) Ba(g) Ba (g) Ba (aq) BaCl2(s) BACO3(s) BaO(s) BASO4(s) 175.6 1649.9 -538.36 -806.06 -1219 -548.1 -1465 a CO(g) - Ta CO2(g) 100 CO2(aq) CO, (aq) HCO3 (aq) H,CO3(aq) CH4(g) or I C,H2(g) CH4(g) CHo(g) -137.2 -394.4 -386.2 -528.10 587.06 -623.42 -50.81 197.5 213.7 121 -53.1 95.0 191 13 - 560.7 D -810.9 Appendix B Standard Thermodynamic Values for Selected Substances A-6 h8 126 KOL 112 72.07 M 132 AG (kJ/mol) GTS--1139 - 520.4 -1353 AH (kJ/mol) Substance Substance or lon AH (kJ/mol) AG (kJ/mol) (J/mol-K) or lon (J/mol-K) -71.5 -53.7 -68.6 Fe* (aq) FeCl2(s) FeCl,(s) FeO(s) Fe;O,(s) Fe O4(s) Lead Pb(s) Pb2 (aq) PbCl2(s) PbO(s) PbO2(s) PbS(s) PBSO4(s) -132 CHCI() CC(e) CCLD COCl,(8) 203 309.7 214.4 283.74 -87.9 -341.8 -399.5 -272.0 - 825.5 -84.94 -302.3 -334.1 -251 4 -743.6 -1018 186.1 200.85 219.22 229.5 269.9 310 172.8 238 127 219 91.6 129.0 164 282.6 -74.87 227 -96.0 -139 -220 113 117.9 142 209 68.36 -32.89 -24.5 - 16.7 124.5 Boron B(B-rhombo- hedral) BF3(g) BCI3(g) B2H6(g) B2O3(s) H3BO3(s) Bromine Br(1) Br2(g) Br(g) Br (g) Br (aq) HBr(g) Cadmium Cd(s) Cd(g) Cd (aq) CdS(s) Calcium Ca(s) 5.87 206 52.47 Cesium Cs(s) Cs(g) "() Cs"(aq) 60.75 87.400 145.3 -84.667 -105 -126 49.0 - 201.2 -238.6 -116 -410 85.15 175.5 169.72 133 -1121 -1120.3 254.0 76.7 -1137.0 49,7 -403.8 -388.7 290.0 C3Hg(g) C4H10(8) 3 C,H6(1) 88.83 CH;OH(g) Co.CA CH3OH(I) 152.23 HCHO(g) 200 HCOO (aq) НСООН () 86.6 232.0 53.8 458.5 -248 554.7 427.1 282.0 525.4 -414 64.785 21 Cs CsF(s) CSCI(s) CsBr(s) CsI(s) 35 1.6 -24.3 88 -359 -1272 -1094.3 -1193 -969.01 -314 -198 -219.0 -161.9 -442.8 101.18 136 -395 -337 -218 -276.6 68.70 76.6 -166.2 -383 121 -333 130 -98.3 -918.39 -110 -96.7 91.3 147 Chlorine 0. -335 -811.24 Cl2(g) Cl(g) CI(8) CI (aq) HCI(g) HCI(aq) CIO2(8) Cl,0(g) Chromium 223.0 165.1 153.25 55.10 186.79 55.06 256.7 266.1 Lithium 3.13 nM 245.38 82.40 174.90 -346 121.0 -234 -167.46 105.0 -240 30.91 111.9 -218.9 -120.9 -36.3 10 -409 -410 Li(s) Li(g) Li (g) Li*(aq) LiF(s) LICI(s) LiBr(s) Lil(s) Magnesium Mg(s) Mg(g) Mg2"(g) Mg²*(aq) MgCl2(s) MGCO3(s) MgO(s) Mg,N2(s) Manganese Mn(s, a) Mn*(aq) MnO2(s) MnO4 (ag) Mercury 158.64 Hg(1) Hg(g) Hg*(aq) Hg22*(aq) HgCl2(s) Hg,Cl2(s) HgO(s) Nitrogen N2(g) N(g) N20(g) 2 NO(g) 70.21 180.67 NO2(g) 29.10 138.67 -356 -168.6 - 174.8 161 128 Co HCOOH(aq) -131.17 -95.30 - 131.17 -235.1 687.163 649.989 - 102.82 80.71 CH5OH(g) n 198.59 CH5OH(I) a0 CH3CH0(g) 51.5a CH3COOH(1) C,H12O6(s) 132.91 -92.31 -167.46 102 80.3 161 -278.46 -616.9 -277.63 -293.8 14 266 160 212.1 360.24 118 201.7 -588.7 -133.7 -392 -910.56 - 1544.3 166 35.66 59.30 74.1 85.8 -53.5 -166 -487.0 - 1273.3 -2221.7 151 135 105 120 -408 -384 97.9 -351 -342 -270 -270 Cr(s) Cr*(aq) CrO4 (ag) Cr20,2 (aq) Copper Cu(s) Cu(g) Cu "(ag) Cu*(aq) Cu,O(s) CuO(s) Cu S(s) CuS(s) Fluorine 23.8 78.20 167.64 - 1971 -863.2 -1461 112.8 -72.38 -144 -61.1 C12H22O1(s) CN (aq) HCN(g) HCN() HCN(aq) 32.69 148.55 -77.74 -706.3 38 214 150 2351 -461.96 115 125 -1257 -141 1OH 71 112.8 121 112 00 129 -456.01 118 89.630 65.86 26.9 33.1 M 166.29 -641.6 237.79 151.0 41.6 105 -592.1 341.1 51.9 64.39 - 168.6 0. 66.9 301.4 -1112 - 1028 154.78 117 50.2 -26 64.98 -146.0 -130 -86.2 120.9 -53.6 66.5 192.6 158.9 63.6 -601.2 -569.0 N CS2(g) 87.9 -83.7 Ca(g) Ca (g) Ca (aq) CaF2(s) CaCl2(s) 234 179 -98.7 93.1 42.63 L-401 - 461 -553.04 -55.2 CS2(/) CH3CI(g) -60.2 1934.1 -542.96 -1215 -795.0 88 -63.2 -157.3 68.87 -117 -1162 -750.2 31.8 84 CH2Cl2() (соntinueg -79.5 -219 -520.9 -518.4 114 -223 -53.1 -466.1 53.1 190 -425.1 0 OH 202.7 F2(g) F(g) F (8) F (aq) HF(g) *All values at 298 K. 78.9 -255.6 61.8 76.027 -262.5 -276.5 -9.6 -275 145.47 61.30 31.8 -329.1 -273 174.87 -32 171 164.4 173.67 172 Hydrogen e H2(8) H(g) H*(aq) H(8) 153.6 -184 84.5 -230 144 130.6 264.9 -210.66 218.0 203.30 114.60 196 Appendix B Standard Thermodynamic Values for Selected Substances -90.79 -58.50 70.27 A-7 1536.3 201 Substance AH (kJ/mol) 1517.1 108.83 AG (kJ/mol) S° Substance AH (kJ/mol) - 203 AG (kJ/mol) lodine 191.5 153.2 219.7 210.65 239.9 304.3 346 178 193 or lon (J/mol-K) or lon 473 82.05 90.29 (J/mol-K) 456 104.2 86.60 1(s) 1(g) I(g) I (g) I (aq) HI(g) NO, (aq) HNO3(1) HNO,(aq) NF3(g) NOCI(g) NH,CI(s) Охудen O2(g) O(g) O3(8) OH (aq) H2O(g) H,O() H,O2() H2O2(aq) Phosphorus Pa(s, white) P(g) P(s, red) P2(g) P4(g) PC13(g) PCI3() PCI5(g) PCI5(s) P.O106) PO (aq) НРО, (ад) H2PO4 (aq) H PO4(aq) Potassium K(s) K(g) K*(g) K*(aq) -206.57 116.14 -110.5 -79.914 146 - 185 - 109.72 -95.939 AgF(s) AgCI(s) AgBr(s) AgI(s) AGNO3(s) Ag2S(s) Sodium Na(s) Na(g) Na (g) Na (aq) NaF(s) NaCl(s) NaBr(s) NaOH(s) NazCO3(s) NaHCO,(s) Nal(s) Strontium Sr(s) Sr(g) S*(g) Sr"(aq) SrCl2(s) SrCO3(s) SrO(s) STSO4(s) Sulfur S(rhombic) S(monoclinic) S(g) S2(8) Sg(g) s (aq) HS (aq) H2S(g) H2S(aq) SO-(g) SO:(g) SO (aq) HSO4 (aq) H2SO4(1) H2SO4(aq) 84 62.442 -173.23 -206.57 155.6 19.38 260.58 -127.03 96.11 106.8 - 194.7 -110.5 -83.3 66.07 -203.0 146 -99.51 107.1 33.2 51 -125 51.71 260.6 -62.38 -66.32 114 128.2 146 NO4(g) N2O5(g) N2O5(s) NH3(8) NH3(aq) N2H4(1) 9.16 97.7 261.6 94.6 -45.06 -31.8 19.1 -40.3 -55.94 25.9 -51.67 1.3 109.4 206.33 -314.4 11 118 Iron -43.1 114 205.0 160.95 238.82 - 10.54 51. 446 Fe(s) Fe (aq) -45.9 -16 249.2 143 231.7 0. 107.76 609.839 -239.66 77.299 153.61 27.3 - 80.83 26.7 110 121.2 163 574.877 147.85 -47.7 - 10.5 -293 -229.94 -157.30 50.63 149.2 -261.87 -545.1 60.2 -241.826 -285.840 -228.60 -575.4 188.72 69.940 110 144 51.21 72.12 86.82 64.454 139 102 (continued -237.192 - 120.4 - 134.1 -411.1 -384.0 -349 -379.53 - 1048.1 -851.9 -285 -187.8 -361 -425.609 - 1130.8 -947.7 - 288 - 191.2 41.1 163.1 314.6 98.5 278.3 -12.1 -17.6 22.8 144 104 54.4 218 280 312 58.9 24.5 164 110 164.54 - 287 -268 1784 -545.51 -557.3 -39 -320 -402 -272 217 -323 353 -828.4 -781.2 117 -1138 -1218 - 592.0 - 1445 97.1 -443.5 -2984 55.5 122 - 562.4 -2698 - 1013 - 1082 - 1135 229 -218 - 36 -1266 - 1334 -1281 -1285 89.1 0. 31.9 0.3 279 129 0.096 239 -1277 - 1019 228 32.6 168 64.672 80.1 228.1 101 49.1 160.23 154.47 89.2 60.7 430.211 41.8 83.7 22 514.197 -251.2 -568.6 -436.7 -394 -328 -424.8 -397.7 -432.75 481.202 -17.7 - 20.2 - 39 -296.8 103 12.6 61.1 205.6 -282.28 -33 -27.4 66.55 KF(s) KCI(s) KBr(s) KI(s) КОН() KCIO3(s) KCIO4(s) Rubidium -538.9 -409.2 - 380 -323 -379.1 82.59 95.94 106.39 78.87 122 -300.2 248.1 256.66 -396 -907.51 - 885.75 -813.989 -907.51 -371 -741.99 -752.87 -690.059 17 143.1 - 296.3 - 303.2 126.9 156.90 17 151.0 -741.99 Tin 69.5 169.99 Rb(s) Rb(g) Rb*(g) Rb*(aq) -246 RbF(s) RBCI(s) RbBr(s) Rbl(s) Silicon Si(s) SiF (g) SiO2(s) Silver Sn(white) Sn(gray) SnCL(1) SnO2(s) Titanium 51.5 44.8 259 52.3 85.81 55.86 4.6 -474.0 495.04 3 -545.2 -580.7 -282.2 124 -519.7 -549.28 -435.35 - 389.2 -328 95.90 108.3 118.0 -407.8 30.7 252.3 50.6 0. -378.1 -326 Ti(s) TICL() TiO2(s) - 804.2 -944.0 -737.2 -888.8 Zinc 18.0 282.4 41.6 Zn(s) Zn(g) Zn*(aq) ZnO(s) ZnS(s, zinc blende) -1614.9 - 1572.7 94.93 160.9 130.5 -856.5 41.5 - 106.5 43.9 57.7 -910.9 -147.21 -152.4 - 348.0 -318.2 - 198 42.702 172.892 Ag(s) Ag(g) Ag *(aq) -203 250.4 289.2 105.9 77.111 73.93
Transcribed Image Text:Appendix B Standard Thermodynamic Values for Selected Substances* ΔΗ (kJ/mol) AG (kJ/mol) S° Substance AH? (kJ/mol) AG (kJ/mol) or lon (J/mol-K) Substance or lon (J/mol-K) 10 CaCO,(s) IS CaO(s) Dr Ca(OH)2(s) Ca3(PO4)2(s) CASO4(s) 20.87 -1206.9 -1128.8 92.9 -603.5 -898.56 -3899 - 1320.3 38.2 83.39 263 -635.1 e (g) -986.09 -4138 Aluminum e 28.3 -481.2 -313 -628.9 Al(s) Al"(ag) AICI(s) Al>Os(s) Barium Ba(s) -524.7 107 -1432.7 110.7 50.94 Carbon -704.2 -1676 -1582 5.686 2.439 158.0 C(graphite) 0. 2.866 1.896 715.0 -110.5 -393.5 -412.9 -676.26 -691.11 -698.7 62.5 O C(diamond) 669.6 144.8 170.28 C(g) Ba(g) Ba (g) Ba (aq) BaCl2(s) BACO3(s) BaO(s) BASO4(s) 175.6 1649.9 -538.36 -806.06 -1219 -548.1 -1465 a CO(g) - Ta CO2(g) 100 CO2(aq) CO, (aq) HCO3 (aq) H,CO3(aq) CH4(g) or I C,H2(g) CH4(g) CHo(g) -137.2 -394.4 -386.2 -528.10 587.06 -623.42 -50.81 197.5 213.7 121 -53.1 95.0 191 13 - 560.7 D -810.9 Appendix B Standard Thermodynamic Values for Selected Substances A-6 h8 126 KOL 112 72.07 M 132 AG (kJ/mol) GTS--1139 - 520.4 -1353 AH (kJ/mol) Substance Substance or lon AH (kJ/mol) AG (kJ/mol) (J/mol-K) or lon (J/mol-K) -71.5 -53.7 -68.6 Fe* (aq) FeCl2(s) FeCl,(s) FeO(s) Fe;O,(s) Fe O4(s) Lead Pb(s) Pb2 (aq) PbCl2(s) PbO(s) PbO2(s) PbS(s) PBSO4(s) -132 CHCI() CC(e) CCLD COCl,(8) 203 309.7 214.4 283.74 -87.9 -341.8 -399.5 -272.0 - 825.5 -84.94 -302.3 -334.1 -251 4 -743.6 -1018 186.1 200.85 219.22 229.5 269.9 310 172.8 238 127 219 91.6 129.0 164 282.6 -74.87 227 -96.0 -139 -220 113 117.9 142 209 68.36 -32.89 -24.5 - 16.7 124.5 Boron B(B-rhombo- hedral) BF3(g) BCI3(g) B2H6(g) B2O3(s) H3BO3(s) Bromine Br(1) Br2(g) Br(g) Br (g) Br (aq) HBr(g) Cadmium Cd(s) Cd(g) Cd (aq) CdS(s) Calcium Ca(s) 5.87 206 52.47 Cesium Cs(s) Cs(g) "() Cs"(aq) 60.75 87.400 145.3 -84.667 -105 -126 49.0 - 201.2 -238.6 -116 -410 85.15 175.5 169.72 133 -1121 -1120.3 254.0 76.7 -1137.0 49,7 -403.8 -388.7 290.0 C3Hg(g) C4H10(8) 3 C,H6(1) 88.83 CH;OH(g) Co.CA CH3OH(I) 152.23 HCHO(g) 200 HCOO (aq) НСООН () 86.6 232.0 53.8 458.5 -248 554.7 427.1 282.0 525.4 -414 64.785 21 Cs CsF(s) CSCI(s) CsBr(s) CsI(s) 35 1.6 -24.3 88 -359 -1272 -1094.3 -1193 -969.01 -314 -198 -219.0 -161.9 -442.8 101.18 136 -395 -337 -218 -276.6 68.70 76.6 -166.2 -383 121 -333 130 -98.3 -918.39 -110 -96.7 91.3 147 Chlorine 0. -335 -811.24 Cl2(g) Cl(g) CI(8) CI (aq) HCI(g) HCI(aq) CIO2(8) Cl,0(g) Chromium 223.0 165.1 153.25 55.10 186.79 55.06 256.7 266.1 Lithium 3.13 nM 245.38 82.40 174.90 -346 121.0 -234 -167.46 105.0 -240 30.91 111.9 -218.9 -120.9 -36.3 10 -409 -410 Li(s) Li(g) Li (g) Li*(aq) LiF(s) LICI(s) LiBr(s) Lil(s) Magnesium Mg(s) Mg(g) Mg2"(g) Mg²*(aq) MgCl2(s) MGCO3(s) MgO(s) Mg,N2(s) Manganese Mn(s, a) Mn*(aq) MnO2(s) MnO4 (ag) Mercury 158.64 Hg(1) Hg(g) Hg*(aq) Hg22*(aq) HgCl2(s) Hg,Cl2(s) HgO(s) Nitrogen N2(g) N(g) N20(g) 2 NO(g) 70.21 180.67 NO2(g) 29.10 138.67 -356 -168.6 - 174.8 161 128 Co HCOOH(aq) -131.17 -95.30 - 131.17 -235.1 687.163 649.989 - 102.82 80.71 CH5OH(g) n 198.59 CH5OH(I) a0 CH3CH0(g) 51.5a CH3COOH(1) C,H12O6(s) 132.91 -92.31 -167.46 102 80.3 161 -278.46 -616.9 -277.63 -293.8 14 266 160 212.1 360.24 118 201.7 -588.7 -133.7 -392 -910.56 - 1544.3 166 35.66 59.30 74.1 85.8 -53.5 -166 -487.0 - 1273.3 -2221.7 151 135 105 120 -408 -384 97.9 -351 -342 -270 -270 Cr(s) Cr*(aq) CrO4 (ag) Cr20,2 (aq) Copper Cu(s) Cu(g) Cu "(ag) Cu*(aq) Cu,O(s) CuO(s) Cu S(s) CuS(s) Fluorine 23.8 78.20 167.64 - 1971 -863.2 -1461 112.8 -72.38 -144 -61.1 C12H22O1(s) CN (aq) HCN(g) HCN() HCN(aq) 32.69 148.55 -77.74 -706.3 38 214 150 2351 -461.96 115 125 -1257 -141 1OH 71 112.8 121 112 00 129 -456.01 118 89.630 65.86 26.9 33.1 M 166.29 -641.6 237.79 151.0 41.6 105 -592.1 341.1 51.9 64.39 - 168.6 0. 66.9 301.4 -1112 - 1028 154.78 117 50.2 -26 64.98 -146.0 -130 -86.2 120.9 -53.6 66.5 192.6 158.9 63.6 -601.2 -569.0 N CS2(g) 87.9 -83.7 Ca(g) Ca (g) Ca (aq) CaF2(s) CaCl2(s) 234 179 -98.7 93.1 42.63 L-401 - 461 -553.04 -55.2 CS2(/) CH3CI(g) -60.2 1934.1 -542.96 -1215 -795.0 88 -63.2 -157.3 68.87 -117 -1162 -750.2 31.8 84 CH2Cl2() (соntinueg -79.5 -219 -520.9 -518.4 114 -223 -53.1 -466.1 53.1 190 -425.1 0 OH 202.7 F2(g) F(g) F (8) F (aq) HF(g) *All values at 298 K. 78.9 -255.6 61.8 76.027 -262.5 -276.5 -9.6 -275 145.47 61.30 31.8 -329.1 -273 174.87 -32 171 164.4 173.67 172 Hydrogen e H2(8) H(g) H*(aq) H(8) 153.6 -184 84.5 -230 144 130.6 264.9 -210.66 218.0 203.30 114.60 196 Appendix B Standard Thermodynamic Values for Selected Substances -90.79 -58.50 70.27 A-7 1536.3 201 Substance AH (kJ/mol) 1517.1 108.83 AG (kJ/mol) S° Substance AH (kJ/mol) - 203 AG (kJ/mol) lodine 191.5 153.2 219.7 210.65 239.9 304.3 346 178 193 or lon (J/mol-K) or lon 473 82.05 90.29 (J/mol-K) 456 104.2 86.60 1(s) 1(g) I(g) I (g) I (aq) HI(g) NO, (aq) HNO3(1) HNO,(aq) NF3(g) NOCI(g) NH,CI(s) Охудen O2(g) O(g) O3(8) OH (aq) H2O(g) H,O() H,O2() H2O2(aq) Phosphorus Pa(s, white) P(g) P(s, red) P2(g) P4(g) PC13(g) PCI3() PCI5(g) PCI5(s) P.O106) PO (aq) НРО, (ад) H2PO4 (aq) H PO4(aq) Potassium K(s) K(g) K*(g) K*(aq) -206.57 116.14 -110.5 -79.914 146 - 185 - 109.72 -95.939 AgF(s) AgCI(s) AgBr(s) AgI(s) AGNO3(s) Ag2S(s) Sodium Na(s) Na(g) Na (g) Na (aq) NaF(s) NaCl(s) NaBr(s) NaOH(s) NazCO3(s) NaHCO,(s) Nal(s) Strontium Sr(s) Sr(g) S*(g) Sr"(aq) SrCl2(s) SrCO3(s) SrO(s) STSO4(s) Sulfur S(rhombic) S(monoclinic) S(g) S2(8) Sg(g) s (aq) HS (aq) H2S(g) H2S(aq) SO-(g) SO:(g) SO (aq) HSO4 (aq) H2SO4(1) H2SO4(aq) 84 62.442 -173.23 -206.57 155.6 19.38 260.58 -127.03 96.11 106.8 - 194.7 -110.5 -83.3 66.07 -203.0 146 -99.51 107.1 33.2 51 -125 51.71 260.6 -62.38 -66.32 114 128.2 146 NO4(g) N2O5(g) N2O5(s) NH3(8) NH3(aq) N2H4(1) 9.16 97.7 261.6 94.6 -45.06 -31.8 19.1 -40.3 -55.94 25.9 -51.67 1.3 109.4 206.33 -314.4 11 118 Iron -43.1 114 205.0 160.95 238.82 - 10.54 51. 446 Fe(s) Fe (aq) -45.9 -16 249.2 143 231.7 0. 107.76 609.839 -239.66 77.299 153.61 27.3 - 80.83 26.7 110 121.2 163 574.877 147.85 -47.7 - 10.5 -293 -229.94 -157.30 50.63 149.2 -261.87 -545.1 60.2 -241.826 -285.840 -228.60 -575.4 188.72 69.940 110 144 51.21 72.12 86.82 64.454 139 102 (continued -237.192 - 120.4 - 134.1 -411.1 -384.0 -349 -379.53 - 1048.1 -851.9 -285 -187.8 -361 -425.609 - 1130.8 -947.7 - 288 - 191.2 41.1 163.1 314.6 98.5 278.3 -12.1 -17.6 22.8 144 104 54.4 218 280 312 58.9 24.5 164 110 164.54 - 287 -268 1784 -545.51 -557.3 -39 -320 -402 -272 217 -323 353 -828.4 -781.2 117 -1138 -1218 - 592.0 - 1445 97.1 -443.5 -2984 55.5 122 - 562.4 -2698 - 1013 - 1082 - 1135 229 -218 - 36 -1266 - 1334 -1281 -1285 89.1 0. 31.9 0.3 279 129 0.096 239 -1277 - 1019 228 32.6 168 64.672 80.1 228.1 101 49.1 160.23 154.47 89.2 60.7 430.211 41.8 83.7 22 514.197 -251.2 -568.6 -436.7 -394 -328 -424.8 -397.7 -432.75 481.202 -17.7 - 20.2 - 39 -296.8 103 12.6 61.1 205.6 -282.28 -33 -27.4 66.55 KF(s) KCI(s) KBr(s) KI(s) КОН() KCIO3(s) KCIO4(s) Rubidium -538.9 -409.2 - 380 -323 -379.1 82.59 95.94 106.39 78.87 122 -300.2 248.1 256.66 -396 -907.51 - 885.75 -813.989 -907.51 -371 -741.99 -752.87 -690.059 17 143.1 - 296.3 - 303.2 126.9 156.90 17 151.0 -741.99 Tin 69.5 169.99 Rb(s) Rb(g) Rb*(g) Rb*(aq) -246 RbF(s) RBCI(s) RbBr(s) Rbl(s) Silicon Si(s) SiF (g) SiO2(s) Silver Sn(white) Sn(gray) SnCL(1) SnO2(s) Titanium 51.5 44.8 259 52.3 85.81 55.86 4.6 -474.0 495.04 3 -545.2 -580.7 -282.2 124 -519.7 -549.28 -435.35 - 389.2 -328 95.90 108.3 118.0 -407.8 30.7 252.3 50.6 0. -378.1 -326 Ti(s) TICL() TiO2(s) - 804.2 -944.0 -737.2 -888.8 Zinc 18.0 282.4 41.6 Zn(s) Zn(g) Zn*(aq) ZnO(s) ZnS(s, zinc blende) -1614.9 - 1572.7 94.93 160.9 130.5 -856.5 41.5 - 106.5 43.9 57.7 -910.9 -147.21 -152.4 - 348.0 -318.2 - 198 42.702 172.892 Ag(s) Ag(g) Ag *(aq) -203 250.4 289.2 105.9 77.111 73.93
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