6. Balance each skeleton reaction, use Appendix D to calcu- late Ell, and state whether the reaction is spontaneous: (a) Mn²*(aq) + Cơ³*(aq) –→ MnO2(s) + Co²*(aq) [acidic] (b) AgCl(s) + NO(g) → Ag(s) + Cl-(aq) + NO;¯(aq) [acidic] · cell

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Chapter17: Electrochemistry
Section: Chapter Questions
Problem 24E: For each reaction listed, determine its standard cell potential at 25 C and whether the reaction is...
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Galvanic Cell 

Balance each skeleton reaction, use Appendix D to calcu-
6.
late Eell, and state whether the reaction is spontaneous:
(a) Mn²*(aq) + Co³*(aq) –→ Mn0,(8) + Co²*(aq) [acidic]
(b) AgCl(s) + NO(g) → Ag(s) + Cl¯(aq) + N0,¬(aq) [acidic]
-
Transcribed Image Text:Balance each skeleton reaction, use Appendix D to calcu- 6. late Eell, and state whether the reaction is spontaneous: (a) Mn²*(aq) + Co³*(aq) –→ Mn0,(8) + Co²*(aq) [acidic] (b) AgCl(s) + NO(g) → Ag(s) + Cl¯(aq) + N0,¬(aq) [acidic] -
Half-Reaction
E° (V)
F;(g) + 2e= 2F (aq)
Os(g) + 2H*(aq) + 2e¯ 0,(g) + H;O(I)
Co* (aq) + e= Co*(aq)
H,O2(aq) + 2H (aq) + 2e 2H,O()
PbO,(s) + 3H*(aq) + HSO, (aq) + 2e PbSO,(8) + 2H;O(I)
Ce*(aq) + e=Ce*(aq)
MnO, (aq) + 8H*(aq) + Se = Mn²*(aq) + 4H;O(1)
Au* (aq) + 3e Au(s)
Cl(g) + 2e= 2C1 (aq)
Cr;0, (aq) + 14H*(aq) + 6c¯ 20* (aq) + 7H,0(1)
MnO,(s) + 4H* (aq) + 2e¯ = Mn*(aq) + 2H;O(1)
O:(g) + 4H (aq) + 4e
Brz() + 2e 2B1¯(aq)
NO, (aq) + 4H* (aq) + 3e NO(g) + 2H,O(1)
2Hg**(aq) + 2e =Hg;²*(aq)
Hgz" (aq) + 2e 2Hg()
Ag*(aq) + e= Ag(s)
Fe" (aq) + e= Fe*(aq)
O,(g) + 2H*(aq) + 2e¯ H;0,(aq)
MnO, (aq) + 2H;O(1) + 3e¯ MnO(s) + 40H (aq)
I(s) + 2e 21 (aq)
O,(g) + 2H;0() + 4c¯= 40H"(aq)
Cu* (aq) + 2e Cu(s)
+2.87
+2.07
+1.82
+1.77
+1.70
+1.61
+1.51
+1.50
+1.36
+1.33
+1.23
= 2H;0(1)
+1.23
+1.07
+0.96
+0.92
+0.85
+0.80
+0.77
+0.68
+0.59
+0.53
+0.40
+0.34
Sn** (ag) + 2e = Sn²* (aq)
2H*(aq) + 2e= Hạ(g)
Pb?* (aq) + 2e Pb(s)
Sn* (aq) + 2e Sn(s)
N2(g) + SH*(aq) + 4c¯ N,H,* (aq)
Ni (aq) + 2e = Ni(s)
Co* (aq) + 2e Co(s)
PbSO,(s) + H*(aq) + 2e¯ Pb(s) + HSO,¯(aq)
Cd* (aq) + 2e Cd(s)
Fe*(aq) + 2e Fe(s)
Cr*(aq) + 3e Cr(s)
Zn* (aq) + 2e Zn(s)
2H,0(1) + 2e = H2(g) + 20H¯ (aq)
C*(ag) + 2e Cr(s)
Mn2*(aq) + 2e Mn(s)
AlP" (aq) + 3e Al(s)
Mg* (aq) + 2e" = Mg(s)
Na (aq) + e = Na(s)
Ca* (aq) + 2e Ca(s)
Sr*(ag) + 2e Sr(s)
Ba" (aq) + 2e
K*(aq) +e= K(s)
Li" (aq) +e 2 Li(s)
+0.13
0.00
-0.13
-0.14
-0.23
--0.25
-0.28
-0.31
-0.40
-0.44
-0.74
-0.76
-0.83
-0.91
-1.18
-1.66
-2.37
-2.71
-2.87
-2.89
* Ba(s)
-2.90
-2.93
-3.05
Transcribed Image Text:Half-Reaction E° (V) F;(g) + 2e= 2F (aq) Os(g) + 2H*(aq) + 2e¯ 0,(g) + H;O(I) Co* (aq) + e= Co*(aq) H,O2(aq) + 2H (aq) + 2e 2H,O() PbO,(s) + 3H*(aq) + HSO, (aq) + 2e PbSO,(8) + 2H;O(I) Ce*(aq) + e=Ce*(aq) MnO, (aq) + 8H*(aq) + Se = Mn²*(aq) + 4H;O(1) Au* (aq) + 3e Au(s) Cl(g) + 2e= 2C1 (aq) Cr;0, (aq) + 14H*(aq) + 6c¯ 20* (aq) + 7H,0(1) MnO,(s) + 4H* (aq) + 2e¯ = Mn*(aq) + 2H;O(1) O:(g) + 4H (aq) + 4e Brz() + 2e 2B1¯(aq) NO, (aq) + 4H* (aq) + 3e NO(g) + 2H,O(1) 2Hg**(aq) + 2e =Hg;²*(aq) Hgz" (aq) + 2e 2Hg() Ag*(aq) + e= Ag(s) Fe" (aq) + e= Fe*(aq) O,(g) + 2H*(aq) + 2e¯ H;0,(aq) MnO, (aq) + 2H;O(1) + 3e¯ MnO(s) + 40H (aq) I(s) + 2e 21 (aq) O,(g) + 2H;0() + 4c¯= 40H"(aq) Cu* (aq) + 2e Cu(s) +2.87 +2.07 +1.82 +1.77 +1.70 +1.61 +1.51 +1.50 +1.36 +1.33 +1.23 = 2H;0(1) +1.23 +1.07 +0.96 +0.92 +0.85 +0.80 +0.77 +0.68 +0.59 +0.53 +0.40 +0.34 Sn** (ag) + 2e = Sn²* (aq) 2H*(aq) + 2e= Hạ(g) Pb?* (aq) + 2e Pb(s) Sn* (aq) + 2e Sn(s) N2(g) + SH*(aq) + 4c¯ N,H,* (aq) Ni (aq) + 2e = Ni(s) Co* (aq) + 2e Co(s) PbSO,(s) + H*(aq) + 2e¯ Pb(s) + HSO,¯(aq) Cd* (aq) + 2e Cd(s) Fe*(aq) + 2e Fe(s) Cr*(aq) + 3e Cr(s) Zn* (aq) + 2e Zn(s) 2H,0(1) + 2e = H2(g) + 20H¯ (aq) C*(ag) + 2e Cr(s) Mn2*(aq) + 2e Mn(s) AlP" (aq) + 3e Al(s) Mg* (aq) + 2e" = Mg(s) Na (aq) + e = Na(s) Ca* (aq) + 2e Ca(s) Sr*(ag) + 2e Sr(s) Ba" (aq) + 2e K*(aq) +e= K(s) Li" (aq) +e 2 Li(s) +0.13 0.00 -0.13 -0.14 -0.23 --0.25 -0.28 -0.31 -0.40 -0.44 -0.74 -0.76 -0.83 -0.91 -1.18 -1.66 -2.37 -2.71 -2.87 -2.89 * Ba(s) -2.90 -2.93 -3.05
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