Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**Example Problem: Analysis of NMR Spectrum**
**Chemical Data:**
- **Chemical Formula:** C₅H₁₀O₂
- **IR Spectrum:** Strong peak at 1750 cm⁻¹
**NMR Spectrum Analysis:**
The NMR spectrum presented shows three distinct signals with the following characteristics:
1. **Signal at ~5.0 ppm:**
- Integration: 1H
- This peak may correspond to a hydrogen atom in a deshielded environment, possibly near an electronegative atom or group.
2. **Signal at ~2.0 ppm:**
- Integration: 3H
- This peak suggests a methyl group (CH₃) possibly adjacent to a carbonyl or other electron-withdrawing group.
3. **Signal at ~1.0 ppm:**
- Integration: 6H
- This peak likely represents two equivalent methyl groups, possibly in an alkyl chain or equivalent environment.
**Note:**
The strong IR peak at 1750 cm⁻¹ indicates the presence of a carbonyl group, likely an ester or ketone, which influences the chemical environment of the hydrogen atoms in the molecule.
**Calculation Check:**
- The handwritten note "5×2 = 10 - 10 = 0" suggests a verification of the number of hydrogens in the chemical formula, confirming the spectrum accounts for all hydrogen atoms present.
This analysis can assist in identifying the structure of the compound C₅H₁₀O₂ by combining the NMR and IR data.
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