5. When ß-cartene is oxidized in vivo it breaks in half and forms two molecules of retinal (vitamin A), which is a precursor to the pigment in the retina responsible for vision. The conjugated system of retinal consists of 11 C atoms and one O atom. In the ground state of retinal, each level up to n = 6 is occupied by two electrons. Assuming that this conjugated system behaves like a particle in a box with an average internuclear distance of 140 pm between each pair of atoms, calculate (a) the separation in energy between the ground state and the first excited state in which one electron occupies the state with n = 7, and (b) the wavelength in nanometers of the radiation required to produce a transition between these two states. (c) What does this have to do with the limit of your vision?

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5. When ß-cartene is oxidized in vivo it breaks in half and forms two molecules of retinal (vitamin A), which is a
precursor to the pigment in the retina responsible for vision. The conjugated system of retinal consists of 11 C
atoms and one O atom. In the ground state of retinal, each level up to n = 6 is occupied by two electrons.
Assuming that this conjugated system behaves like a particle in a box with an average internuclear distance of 140
pm between each pair of atoms, calculate (a) the separation in energy between the ground state and the first
excited state in which one electron occupies the state with n = 7, and (b) the wavelength in nanometers of the
radiation required to produce a transition between these two states. (c) What does this have to do with the limit of
your vision?
Transcribed Image Text:5. When ß-cartene is oxidized in vivo it breaks in half and forms two molecules of retinal (vitamin A), which is a precursor to the pigment in the retina responsible for vision. The conjugated system of retinal consists of 11 C atoms and one O atom. In the ground state of retinal, each level up to n = 6 is occupied by two electrons. Assuming that this conjugated system behaves like a particle in a box with an average internuclear distance of 140 pm between each pair of atoms, calculate (a) the separation in energy between the ground state and the first excited state in which one electron occupies the state with n = 7, and (b) the wavelength in nanometers of the radiation required to produce a transition between these two states. (c) What does this have to do with the limit of your vision?
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