5. Nitrogen dioxide can undergo a gas-phase bimolecular reaction to give nitric oxide and oxygen: NO₂ NO₂ → 2 NO + O₂ The temperature-dependence of the bimolecular rate coefficient is shown below. Temperature (K) k (L mol-¹ s¹) 600 700 800 1000 0.46 9.7 130 3100 a) Use this data to determine the activation energy of the reaction. b) Hae sellisia of th

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5. Nitrogen dioxide can undergo a gas-phase bimolecular reaction to give nitric oxide and
oxygen:
NO₂ + NO2 → 2 NO + 0₂
The temperature-dependence of the bimolecular rate coefficient is shown below.
Temperature (K)
k (L mol-¹ s-¹)
600
0.46
700 800
9.7
130
1000
3100
a) Use this data to determine the activation energy of the reaction.
b) Use collision theory and a value of the reaction cross-section of 0.6 nm² to determine
the steric P factor of the above reaction specifically at 1000 K.
Transcribed Image Text:5. Nitrogen dioxide can undergo a gas-phase bimolecular reaction to give nitric oxide and oxygen: NO₂ + NO2 → 2 NO + 0₂ The temperature-dependence of the bimolecular rate coefficient is shown below. Temperature (K) k (L mol-¹ s-¹) 600 0.46 700 800 9.7 130 1000 3100 a) Use this data to determine the activation energy of the reaction. b) Use collision theory and a value of the reaction cross-section of 0.6 nm² to determine the steric P factor of the above reaction specifically at 1000 K.
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