5. Methanamide, CH,NO, is a liquid at 25°C. (a) The complete Lewis electron-dot diagram for methanamide is shown below. *O* H (i) In the molecule, angle x is not 180°. Estimate the observed angle. Justify your answer. (ii) In the molecule, angle y is not 90°. Explain why in terms of electron domains (VSEPR model). (b) Consider a molecule with the formula CH,O,. The structure of this molecule has a geometry around the carbon atom similar to the geometry around carbon in methanamide. In the box provided below, draw the complete Lewis electron-dot diagram for the molecule.

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### Methanamide (CH₃NO) Analysis

#### (a) Lewis Electron-Dot Diagram for Methanamide

The diagram illustrates the connectivity and electron arrangement within a methanamide molecule. The central atom is carbon (C) bonded to an oxygen (O) atom, a nitrogen (N) atom, and a hydrogen (H) atom. The diagram is as follows:

- Carbon is double-bonded to oxygen.
- Carbon is single-bonded to nitrogen with a potential lone pair on the nitrogen.
- Carbon is also single-bonded to a hydrogen atom.
- Nitrogen is bonded to another hydrogen atom.
- Oxygen has two lone pairs of electrons.

#### (a) Discussion Questions

(i) **Angle x Analysis**: 
- Angle x, formed between hydrogen, carbon, and oxygen, is not 180°.
- Estimated Angle: Approximately 120°.
- Justification using the Trigonal Planar Structure: This occurs due to the carbonyl group (C=O) creating a planar arrangement that slightly compresses the angle due to electron repulsion.

(ii) **Angle y Analysis**: 
- Angle y, formed between hydrogen, nitrogen, and carbon, is not 90°.
- Explanation using VSEPR Model: The presence of lone pair on nitrogen causes greater lone pair-bond pair repulsion, making the angle closer to 107°, typical of the tetrahedral arrangement adjusted for lone pairs.

#### (b) CH₂O₂ Analysis

**Structure with Similar Geometry**:
- Consider a molecule CH₂O₂ where carbon's geometry resembles the planar arrangement found in methanamide.
- The goal is to draw the complete Lewis electron-dot diagram for this molecule, considering similar electron domain geometries.

---
This explanation caters to students learning about molecular geometry, bond angles, and electron domain theory using VSEPR.
Transcribed Image Text:### Methanamide (CH₃NO) Analysis #### (a) Lewis Electron-Dot Diagram for Methanamide The diagram illustrates the connectivity and electron arrangement within a methanamide molecule. The central atom is carbon (C) bonded to an oxygen (O) atom, a nitrogen (N) atom, and a hydrogen (H) atom. The diagram is as follows: - Carbon is double-bonded to oxygen. - Carbon is single-bonded to nitrogen with a potential lone pair on the nitrogen. - Carbon is also single-bonded to a hydrogen atom. - Nitrogen is bonded to another hydrogen atom. - Oxygen has two lone pairs of electrons. #### (a) Discussion Questions (i) **Angle x Analysis**: - Angle x, formed between hydrogen, carbon, and oxygen, is not 180°. - Estimated Angle: Approximately 120°. - Justification using the Trigonal Planar Structure: This occurs due to the carbonyl group (C=O) creating a planar arrangement that slightly compresses the angle due to electron repulsion. (ii) **Angle y Analysis**: - Angle y, formed between hydrogen, nitrogen, and carbon, is not 90°. - Explanation using VSEPR Model: The presence of lone pair on nitrogen causes greater lone pair-bond pair repulsion, making the angle closer to 107°, typical of the tetrahedral arrangement adjusted for lone pairs. #### (b) CH₂O₂ Analysis **Structure with Similar Geometry**: - Consider a molecule CH₂O₂ where carbon's geometry resembles the planar arrangement found in methanamide. - The goal is to draw the complete Lewis electron-dot diagram for this molecule, considering similar electron domain geometries. --- This explanation caters to students learning about molecular geometry, bond angles, and electron domain theory using VSEPR.
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