Help with Part A B and C:Ksp Values:Ionic CompoundFormulaKspAluminum hydroxideAl(OH)31.8×10–5Aluminum phosphateAlPO46.3×10–19Barium carbonateBaCO35.1×10–9Barium chromateBaCrO41.2×10–10Barium fluorideBaF21.0×10–6Barium hydroxideBa(OH)25×10–3Barium sulfateBaSO41.1×10–10Barium sulfiteBaSO38×10–7Barium thiosulfateBaS2O31.6×10–6Bismuthyl chlorideBiOCl1.8×10–31Bismuthyl hydroxideBiOOH4×10–10Cadmium carbonateCdCO35.2×10–12Cadmium hydroxideCd(OH)22.5×10–14Cadmium oxalateCdC2O41.5×10–8Cadmium sulfide*CdS8×10–28Calcium carbonateCaCO32.8×10–9Calcium chromateCaCrO47.1×10–4Calcium fluorideCaF25.3×10–9Calcium hydrogen phosphateCaHPO41×10–7Calcium hydroxideCa(OH)25.5×10–6Calcium oxalateCaC2O42.7×10–9Calcium phosphateCa3(PO4)22.0×10–29Calcium sulfateCaSO49.1×10–6Calcium sulfiteCaSO36.8×10–8Chromium(II) hydroxideCr(OH)22×10–16Chromium(III) hydroxideCr(OH)36.3×10–31Cobalt(II) carbonateCoCO31.4×10–13Cobalt(II) hydroxideCo(OH)21.6×10–15Cobalt(III) hydroxideCo(OH)31.6×10–44Cobalt(II) sulfide*CoS4×10–21Copper(I) chlorideCuCl1.2×10–6Copper(I) cyanideCuCN3.2×10–20Copper(I) iodideCuI1.1×10–12Copper(II) arsenateCu3(AsO4)27.6×10–36Copper(II) carbonateCuCO31.4×10–10Copper(II) chromateCuCrO43.6×10–6Copper(II) ferrocyanideCu[Fe(CN)6]1.3×10–16Copper(II) hydroxideCu(OH)22.2×10–20Copper(II) sulfide*CuS6×10–37Iron(II) carbonateFeCO33.2×10–11Iron(II) hydroxideFe(OH)28.0×10–16Iron(II) sulfide*FeS6×10–19Iron(III) arsenateFeAsO45.7×10–21Iron(III) ferrocyanideFe4[Fe(CN)6]33.3×10–41Iron(III) hydroxideFe(OH)34×10–38Iron(III) phosphateFePO41.3×10–22Lead(II) arsenatePb3(AsO4)24×10–36Lead(II) azidePb(N3)22.5×10–9Lead(II) bromidePbBr24.0×10–5Lead(II) carbonatePbCO37.4×10–14Lead(II) chloridePbCl21.6×10–5Lead(II) chromatePbCrO42.8×10–13Lead(II) fluoridePbF22.7×10–8Lead(II) hydroxidePb(OH)21.2×10–15Lead(II) iodidePbI27.1×10–9Lead(II) sulfatePbSO41.6×10–8Lead(II) sulfide*PbS3×10–28Lithium carbonateLi2CO32.5×10–2Lithium fluorideLiF3.8×10–3Lithium phosphateLi3PO43.2×10–9Magnesium ammonium phosphateMgNH4PO42.5×10–13Magnesium arsenateMg3(AsO4)22×10–20Magnesium carbonateMgCO33.5×10–8Magnesium fluorideMgF23.7×10–8Magnesium hydroxideMg(OH)21.8×10–11Magnesium oxalateMgC2O48.5×10–5Magnesium phosphateMg3(PO4)21×10–25Manganese(II) carbonateMnCO31.8×10–11Manganese(II) hydroxideMn(OH)21.9×10–13Manganese(II) sulfide*MnS3×10–14Mercury(I) bromideHg2Br25.6×10–23Mercury(I) chlorideHg2Cl21.3×10–18Mercury(I) iodideHg2I24.5×10–29Mercury(II) sulfide*HgS2×10–53Nickel(II) carbonateNiCO36.6×10–9Nickel(II) hydroxideNi(OH)22.0×10–15Nickel(II) sulfide*NiS3×10–19Scandium fluorideScF34.2×10–18Scandium hydroxideSc(OH)38.0×10–31Silver acetateAgC2H3O22.0×10–3Silver arsenateAg3AsO41.0×10–22Silver azideAgN32.8×10–9Silver bromideAgBr5.0×10–13Silver chlorideAgCl1.8×10–10Silver chromateAg2CrO41.1×10–12Silver cyanideAgCN1.2×10–16Silver iodateAgIO33.0×10–8Silver iodideAgI8.5×10–17Silver nitriteAgNO26.0×10–4Silver sulfateAg2SO41.4×10–5Silver sulfide*Ag2S6×10–51Silver sulfiteAg2SO31.5×10–14Silver thiocyanateAgSCN1.0×10–12Strontium carbonateSrCO31.1×10–10Strontium chromateSrCrO42.2×10–5Strontium fluorideSrF22.5×10–9Strontium sulfateSrSO43.2×10–7Thallium(I) bromideTlBr3.4×10–6Thallium(I) chlorideTlCl1.7×10–4Thallium (I) iodideTlI6.5×10–8Thallium(III) hydroxideTl(OH)36.3×10–46Tin(II) hydroxideSn(OH)21.4×10–28Tin(II) sulfide*SnS1×10–26Zinc carbonateZnCO31.4×10–11Zinc hydroxideZn(OH)21.2×10–17Zinc oxalateZnC2O42.7×10–8Zinc phosphateZn3(PO4)29.0×10–33Zinc sulfide*ZnS2×10–25* Sulfide equilibrium of the type:MS(s) + H2O(l) → ← M2+(aq) + HS–(aq) + OH–(aq>) 5. For those mixtures that result in precipitate formation, identify the precipitate. For those mixturesthat do not result in precipitate formation, explain why. Refer to a table of Kgp values as needed.a. 20.0 mL 0.020 M Ba(NO3)2 mixed with 80.0 mL of a pH 12 buffer.b. 60.0 mL 0.010 M CuSO4 mixed with 40.0 mL 0.010 M K2CO3.c. 40.0 mL 0.10 M MgCl2 mixed with 60.0 mL 0.10 M NANO3.

A precipitate is formed in a double displacement reaction, when any one of the product is sparingly…

Answered: 5. For those mixtures that result in…

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Help with Part A B and C:

Ksp Values:

Ionic CompoundFormulaK_sp

Aluminum hydroxideAl(OH)₃1.8×10^–5

Aluminum phosphateAlPO₄6.3×10^–19

Barium carbonateBaCO₃5.1×10^–9

Barium chromateBaCrO₄1.2×10^–10

Barium fluorideBaF₂1.0×10^–6

Barium hydroxideBa(OH)₂5×10^–3

Barium sulfateBaSO₄1.1×10^–10

Barium sulfiteBaSO₃8×10^–7

Barium thiosulfateBaS₂O₃1.6×10^–6

Bismuthyl chlorideBiOCl1.8×10^–31

Bismuthyl hydroxideBiOOH4×10^–10

Cadmium carbonateCdCO₃5.2×10^–12

Cadmium hydroxideCd(OH)₂2.5×10^–14

Cadmium oxalateCdC₂O₄1.5×10^–8

Cadmium sulfide*CdS8×10^–28

Calcium carbonateCaCO₃2.8×10^–9

Calcium chromateCaCrO₄7.1×10^–4

Calcium fluorideCaF₂5.3×10^–9

Calcium hydrogen phosphateCaHPO₄1×10^–7

Calcium hydroxideCa(OH)₂5.5×10^–6

Calcium oxalateCaC₂O₄2.7×10^–9

Calcium phosphateCa₃(PO₄)₂2.0×10^–29

Calcium sulfateCaSO₄9.1×10^–6

Calcium sulfiteCaSO₃6.8×10^–8

Chromium(II) hydroxideCr(OH)₂2×10^–16

Chromium(III) hydroxideCr(OH)₃6.3×10^–31

Cobalt(II) carbonateCoCO₃1.4×10^–13

Cobalt(II) hydroxideCo(OH)₂1.6×10^–15

Cobalt(III) hydroxideCo(OH)₃1.6×10^–44

Cobalt(II) sulfide*CoS4×10^–21

Copper(I) chlorideCuCl1.2×10^–6

Copper(I) cyanideCuCN3.2×10^–20

Copper(I) iodideCuI1.1×10^–12

Copper(II) arsenateCu₃(AsO₄)₂7.6×10^–36

Copper(II) carbonateCuCO₃1.4×10^–10

Copper(II) chromateCuCrO₄3.6×10^–6

Copper(II) ferrocyanideCu[Fe(CN)₆]1.3×10^–16

Copper(II) hydroxideCu(OH)₂2.2×10^–20

Copper(II) sulfide*CuS6×10^–37

Iron(II) carbonateFeCO₃3.2×10^–11

Iron(II) hydroxideFe(OH)₂8.0×10^–16

Iron(II) sulfide*FeS6×10^–19

Iron(III) arsenateFeAsO₄5.7×10^–21

Iron(III) ferrocyanideFe₄[Fe(CN)₆]₃3.3×10^–41

Iron(III) hydroxideFe(OH)₃4×10^–38

Iron(III) phosphateFePO₄1.3×10^–22

Lead(II) arsenatePb₃(AsO₄)₂4×10^–36

Lead(II) azidePb(N₃)₂2.5×10^–9

Lead(II) bromidePbBr₂4.0×10^–5

Lead(II) carbonatePbCO₃7.4×10^–14

Lead(II) chloridePbCl₂1.6×10^–5

Lead(II) chromatePbCrO₄2.8×10^–13

Lead(II) fluoridePbF₂2.7×10^–8

Lead(II) hydroxidePb(OH)₂1.2×10^–15

Lead(II) iodidePbI₂7.1×10^–9

Lead(II) sulfatePbSO₄1.6×10^–8

Lead(II) sulfide*PbS3×10^–28

Lithium carbonateLi₂CO₃2.5×10^–2

Lithium fluorideLiF3.8×10^–3

Lithium phosphateLi₃PO₄3.2×10^–9

Magnesium ammonium phosphateMgNH₄PO₄2.5×10^–13

Magnesium arsenateMg₃(AsO₄)₂2×10^–20

Magnesium carbonateMgCO₃3.5×10^–8

Magnesium fluorideMgF₂3.7×10^–8

Magnesium hydroxideMg(OH)₂1.8×10^–11

Magnesium oxalateMgC₂O₄8.5×10^–5

Magnesium phosphateMg₃(PO₄)₂1×10^–25

Manganese(II) carbonateMnCO₃1.8×10^–11

Manganese(II) hydroxideMn(OH)₂1.9×10^–13

Manganese(II) sulfide*MnS3×10^–14

Mercury(I) bromideHg₂Br₂5.6×10^–23

Mercury(I) chlorideHg₂Cl₂1.3×10^–18

Mercury(I) iodideHg₂I₂4.5×10^–29

Mercury(II) sulfide*HgS2×10^–53

Nickel(II) carbonateNiCO₃6.6×10^–9

Nickel(II) hydroxideNi(OH)₂2.0×10^–15

Nickel(II) sulfide*NiS3×10^–19

Scandium fluorideScF₃4.2×10^–18

Scandium hydroxideSc(OH)₃8.0×10^–31

Silver acetateAgC₂H₃O₂2.0×10^–3

Silver arsenateAg₃AsO₄1.0×10^–22

Silver azideAgN₃2.8×10^–9

Silver bromideAgBr5.0×10^–13

Silver chlorideAgCl1.8×10^–10

Silver chromateAg₂CrO₄1.1×10^–12

Silver cyanideAgCN1.2×10^–16

Silver iodateAgIO₃3.0×10^–8

Silver iodideAgI8.5×10^–17

Silver nitriteAgNO₂6.0×10^–4

Silver sulfateAg₂SO₄1.4×10^–5

Silver sulfide*Ag₂S6×10^–51

Silver sulfiteAg₂SO₃1.5×10^–14

Silver thiocyanateAgSCN1.0×10^–12

Strontium carbonateSrCO₃1.1×10^–10

Strontium chromateSrCrO₄2.2×10^–5

Strontium fluorideSrF₂2.5×10^–9

Strontium sulfateSrSO₄3.2×10^–7

Thallium(I) bromideTlBr3.4×10^–6

Thallium(I) chlorideTlCl1.7×10^–4

Thallium (I) iodideTlI6.5×10^–8

Thallium(III) hydroxideTl(OH)₃6.3×10^–46

Tin(II) hydroxideSn(OH)₂1.4×10^–28

Tin(II) sulfide*SnS1×10^–26

Zinc carbonateZnCO₃1.4×10^–11

Zinc hydroxideZn(OH)₂1.2×10^–17

Zinc oxalateZnC₂O₄2.7×10^–8

Zinc phosphateZn₃(PO₄)₂9.0×10^–33

Zinc sulfide*ZnS2×10^–25

* Sulfide equilibrium of the type:

MS(s) + H₂O(l) → ← M²⁺(aq) + HS^–(aq) + OH^–(aq>)

5. For those mixtures that result in precipitate formation, identify the precipitate. For those mixtures
that do not result in precipitate formation, explain why. Refer to a table of Kgp values as needed.
a. 20.0 mL 0.020 M Ba(NO3)2 mixed with 80.0 mL of a pH 12 buffer.
b. 60.0 mL 0.010 M CuSO4 mixed with 40.0 mL 0.010 M K2CO3.
c. 40.0 mL 0.10 M MgCl2 mixed with 60.0 mL 0.10 M NANO3.

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