Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:wWu W
is present in a solution.
You will attempt to convert the aqua complex ions listed above to chloro complex ions, using concentrated
HCl as a source of Cl. For Co", the reaction is
1.1701o
(17-7)
Co(H2O) + 4 C CoCl-+ 6 H20
A general equation for various miethl ions would be
INITAO ot ưoivdo
M(H2O),* + y Cr MCI,y + x H2O
(17-8)
In working with the three metal ions chosen for this experiment, you must decide whether or not there e
visible evidence of formation of a complex ion within a short time period. You will then list the ions on the basis of
how extensive the reaction of EQUATION 17-8 is for a particular amount of Cr, that is, on the basis of the size of
the equilibrium constant for the reaction of EQUATION 17-8.
After comparing chloro complex ions of the three different metal ions, you will compare two different complex
ions of one metal ion. You will investigate the reactions in EQUATIONS 17-7 and 17-9 to determine which reaction
is more extensive for a particular amount of a complexing agent, CF or NCS"; that is, which reaction has a larger
equilibrium constant.
to g A0 arlosd
Ine sales lo a Co(H2O)* + 4 NCS- Co(NCS) + 6 H20
Jin t
sloe doo 30ol
(17-9)
irulon dion nd
1. Pour 5,0 mL of 0.5 M Co(NO:)2 into each of two 20-mL test tubes. Pour 5.0 mL of 0.5 M Cr(NO:), into cach of
oto to anoi

Transcribed Image Text:5. For the equilibrium systems depicted in EQUATIONS 17-7 and 17-9, which has the larger equilibrium constant?
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