5. Find all the symmetry elements in H2O and derive its character table (Assume the bases arelinear, quadratic functions and rotations; x, y, z, x', y, 2, xy, xz, yz, Rr, Ry, Rz)6. Find all the symmetry elements in NH; and derive its character table also.7. (1) Using the x, y, and z coordinates for each atom in XeF4, determine the reduciblerepresentation for all molecular motions (2) And reduce this representation to its irreduciblecomponents (3) And classify these representations into translational, rotational, and vibrationalmodes.8. (1) Using the x, y, and z coordinates for each atom in H20, determine the reduciblerepresentation for all molecular motions. (2) And reduce this representation to its irreduciblecomponents.9. (1) Classify these representations of H20 into a translational, rotational, and vibrationalmode. (2) Do they have a temporary or permanent dipole moment? Please explain it based onthe derived modes.10. (1) Write the corresponding 9 x 9 transformation matrices for the C2, o, (xz) and o, (vz)operations in water and (2) show their Jordan matrices having a similarity.

Answered: 5. Find all the symmetry elements in…

5. Find all the symmetry elements in H2O and derive its character table (Assume the bases are lincar, quadratic functions and rotations; x, y, z, x', y, 2, xy, xz, yz, Rr, Ry, Rz)

Chemistry

10th Edition

ISBN:9781305957404

Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste

Chapter1: Chemical Foundations

Section: Chapter Questions

Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...

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Question

5. Find all the symmetry elements in H2O and derive its character table (Assume the bases are
linear, quadratic functions and rotations; x, y, z, x', y, 2, xy, xz, yz, Rr, Ry, Rz)
6. Find all the symmetry elements in NH; and derive its character table also.
7. (1) Using the x, y, and z coordinates for each atom in XeF4, determine the reducible
representation for all molecular motions (2) And reduce this representation to its irreducible
components (3) And classify these representations into translational, rotational, and vibrational
modes.
8. (1) Using the x, y, and z coordinates for each atom in H20, determine the reducible
representation for all molecular motions. (2) And reduce this representation to its irreducible
components.
9. (1) Classify these representations of H20 into a translational, rotational, and vibrational
mode. (2) Do they have a temporary or permanent dipole moment? Please explain it based on
the derived modes.
10. (1) Write the corresponding 9 x 9 transformation matrices for the C2, o, (xz) and o, (vz)
operations in water and (2) show their Jordan matrices having a similarity.

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