Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:**Task 5: Cyclohexane Conformations**
**Instruction:**
Draw the most stable chair conformation of the cyclohexanes below. Also, assign R/S to each chiral carbon.
**Diagrams:**
1. **Cyclohexane 1:**
- The diagram shows a hexagonal ring representing cyclohexane with one substituent on a wedge and one on a dashed line, indicating different orientations.
2. **Cyclohexane 2:**
- A second cyclohexane ring is illustrated with different substituents. An isopropyl group (i-Pr) and an ethyl group (Et) are depicted, each on a different carbon atom, with orientation indicated by wedges and dashed lines.
3. **Cyclohexane 3:**
- A third cyclohexane structure features substituents drawn similarly to the other diagrams. The ethyl groups (Et) are in different positions compared to the previous diagram.
**Explanation:**
- The task is to draw the most stable chair conformation for the given cyclohexane structures and to determine the stereochemistry (R/S configuration) at each chiral center. The chair conformation is a common structure for cyclohexane due to minimized steric strain.
- Substituents are represented in different orientations (wedge/dashed) to depict their 3D positioning on the ring and affect stability and configuration.
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