5) A solution is made by combining 75.0 mL of 0.0040 M Na2SO4 and 25.0 mL of 0.080 M AgNO3. Calculate the final concentrations of all four ions in solution. The Ksp of Ag2SO4 is 1.5 x 10-5. 75,0ML Na₂ soy 2 50ml. 1002

Appl Of Ms Excel In Analytical Chemistry
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ISBN:9781285686691
Author:Crouch
Publisher:Crouch
Chapter8: Polyfunctional Acids And Bases
Section: Chapter Questions
Problem 6P
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### Problem Statement:
A solution is made by combining 75.0 mL of 0.0040 M Na₂SO₄ and 25.0 mL of 0.080 M AgNO₃. Calculate the final concentrations of all four ions in solution. The \( K_{sp} \) of Ag₂SO₄ is \( 1.5 \times 10^{-5} \).

### Solution Steps:

1. **Volume and Mol Calculations:**
   We have:
   - 75.0 mL of 0.0040 M Na₂SO₄
   - 25.0 mL of 0.080 M AgNO₃
   - Final total volume = 100 mL

2. **Concentration Adjustments for Dilution:**
   For Na₂SO₄:
   \[ C_1 = 0.0040 \, \text{M} \]
   \[ V_1 = 75 \, \text{mL} \]
   \[ V_f = 100 \, \text{mL} \]
   \[ C_f (Na₂SO₄) = C_1 \times \frac{V_1}{V_f} = 0.0040 \times \frac{75}{100} = 0.0030 \, \text{M} \]

   Splitting into ions:
   \[ Na₂SO₄ \rightarrow 2Na^+ + SO₄^{2-} \]
   \[ SO₄^{2-} = 0.0030 \, \text{M} \]
   \[ Na^+ = 2 \times 0.0030 \, \text{M} = 0.0060 \, \text{M} \]

   For AgNO₃:
   \[ C_3 = 0.080 \, \text{M} \]
   \[ V_3 = 25 \, \text{mL} \]
   \[ V_f = 100 \, \text{mL} \]
   \[ C_f (AgNO₃) = C_3 \times \frac{V_3}{V_f} = 0.080 \times \frac{25}{100} = 0.020 \, \text{
Transcribed Image Text:### Problem Statement: A solution is made by combining 75.0 mL of 0.0040 M Na₂SO₄ and 25.0 mL of 0.080 M AgNO₃. Calculate the final concentrations of all four ions in solution. The \( K_{sp} \) of Ag₂SO₄ is \( 1.5 \times 10^{-5} \). ### Solution Steps: 1. **Volume and Mol Calculations:** We have: - 75.0 mL of 0.0040 M Na₂SO₄ - 25.0 mL of 0.080 M AgNO₃ - Final total volume = 100 mL 2. **Concentration Adjustments for Dilution:** For Na₂SO₄: \[ C_1 = 0.0040 \, \text{M} \] \[ V_1 = 75 \, \text{mL} \] \[ V_f = 100 \, \text{mL} \] \[ C_f (Na₂SO₄) = C_1 \times \frac{V_1}{V_f} = 0.0040 \times \frac{75}{100} = 0.0030 \, \text{M} \] Splitting into ions: \[ Na₂SO₄ \rightarrow 2Na^+ + SO₄^{2-} \] \[ SO₄^{2-} = 0.0030 \, \text{M} \] \[ Na^+ = 2 \times 0.0030 \, \text{M} = 0.0060 \, \text{M} \] For AgNO₃: \[ C_3 = 0.080 \, \text{M} \] \[ V_3 = 25 \, \text{mL} \] \[ V_f = 100 \, \text{mL} \] \[ C_f (AgNO₃) = C_3 \times \frac{V_3}{V_f} = 0.080 \times \frac{25}{100} = 0.020 \, \text{
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