5-6. What is the major drawback of trying to distill a 500-µL mixture of liquids, all with boiling points below 200 °C? 5-7. How might you separate the mixture discussed in question 5-6 if distillation were unsuccessful? Explain your choice. 5-8. If starting with an equal mixture of hexane and toluene, approximate the composition of hexane if the vapor at 94 °C is condensed to a liquid using the data presented in Figure 5.6. 5-9. Why do simple distillations require that the components of the mixture to be separated have boiling points that are separated by 40 °C or more? 5-10. Which constituent of an equimolar mixture makes the larger contribution to the vapor pressure of the mixture, the higher or lower boiling component? Explain.
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Introduction
Distillation is a commonly used method in chemistry for separating and purifying different components of a mixture. The process involves heating the mixture to vaporize one or more of its components, then cooling and condensing the vapor back into a liquid.
The principle of distillation is based on the fact that different substances have different boiling points, and therefore can be separated by heating the mixture to a temperature at which one of the components vaporizes while the others remain in a liquid state. The vaporized component is then collected and condensed back into a liquid, while the remaining components are left behind.
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