489 11/ (CH3)2 HCH3 HCH2CH3 HCH(CH3)2 H-C(CH3)3 435 104 (CH3)2CH-Br 285 68 410 98 Bonds to methyl (CH3)2CH- 222 53 397 95 CH3-H 435 104 (CH3)2CH-OH 381 91 381 91 CH3-F 456 109 473 113 CH3-CI 351 84 CH3 H- CH3 Br 70 H3C-C-x 293 CH3 234 56 CH3 356 85 CH3-OH 381 91 (CH3)3C-H 381 91 (CH3)3C-F 444 106 H 464 111 (CH3)3C-CI 331 79 H3C-C-x (CH3);C-Br 272 65 364 87 (CH3)3C-I 209 50 H-F 569 136 CH3CH2-H 410 98 (CH3)3C-OH 381 91 H-CI 431 103 CH;CH2-F 448 107 H-Br 368 88 CH;CH2-CI 339 81 X-X bonds 297 71 CH;CH2-Br 285 68 159 38

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**Table 6.1: Bond Dissociation Energies (ΔH°) of Common Bonds**

This table provides values for bond dissociation energies in both kilojoules per mole (kJ/mol) and kilocalories per mole (kcal/mol) for various common bonds. 

**Bonds to H:**
- H—H: 435 kJ/mol, 104 kcal/mol
- H—CH₃: 435 kJ/mol, 104 kcal/mol
- H—CCH: 410 kJ/mol, 98 kcal/mol
- H—CH(CH₃)₂: 397 kJ/mol, 95 kcal/mol
- H—C(CH₃)₃: 381 kJ/mol, 91 kcal/mol

With aromatic and terminal alkyne bonds:
- Benzene H: 473 kJ/mol, 113 kcal/mol
- H—Ph (Phenyl): 356 kJ/mol, 85 kcal/mol
- Alkyne H: 464 kJ/mol, 111 kcal/mol
- H—H₂C=CH: 364 kJ/mol, 87 kcal/mol

With halogen and hydroxyl bonds:
- H—F: 569 kJ/mol, 136 kcal/mol
- H—Cl: 431 kJ/mol, 103 kcal/mol
- H—Br: 368 kJ/mol, 88 kcal/mol
- H—I: 297 kJ/mol, 71 kcal/mol
- H—OH: 498 kJ/mol, 119 kcal/mol
- H—OCH₂CH₃: 435 kJ/mol, 104 kcal/mol

**C—C Bonds:**
- CH₃—CH₃: 368 kJ/mol, 88 kcal/mol
- CH₃CH₂—CH₃: 356 kJ/mol, 85 kcal/mol
- (CH₃)₂CH—CH₃: 351 kJ/mol, 84 kcal/mol

**Bonds to Methyl (CH₃):**
- CH₃—H: 435 kJ/mol, 104 kcal/mol
- CH₃—F: 456 kJ/mol, 109 kcal/mol
- CH₃—Cl: 351 kJ/mol, 84 kcal/mol
- CH₃—Br: 293 kJ
Transcribed Image Text:**Table 6.1: Bond Dissociation Energies (ΔH°) of Common Bonds** This table provides values for bond dissociation energies in both kilojoules per mole (kJ/mol) and kilocalories per mole (kcal/mol) for various common bonds. **Bonds to H:** - H—H: 435 kJ/mol, 104 kcal/mol - H—CH₃: 435 kJ/mol, 104 kcal/mol - H—CCH: 410 kJ/mol, 98 kcal/mol - H—CH(CH₃)₂: 397 kJ/mol, 95 kcal/mol - H—C(CH₃)₃: 381 kJ/mol, 91 kcal/mol With aromatic and terminal alkyne bonds: - Benzene H: 473 kJ/mol, 113 kcal/mol - H—Ph (Phenyl): 356 kJ/mol, 85 kcal/mol - Alkyne H: 464 kJ/mol, 111 kcal/mol - H—H₂C=CH: 364 kJ/mol, 87 kcal/mol With halogen and hydroxyl bonds: - H—F: 569 kJ/mol, 136 kcal/mol - H—Cl: 431 kJ/mol, 103 kcal/mol - H—Br: 368 kJ/mol, 88 kcal/mol - H—I: 297 kJ/mol, 71 kcal/mol - H—OH: 498 kJ/mol, 119 kcal/mol - H—OCH₂CH₃: 435 kJ/mol, 104 kcal/mol **C—C Bonds:** - CH₃—CH₃: 368 kJ/mol, 88 kcal/mol - CH₃CH₂—CH₃: 356 kJ/mol, 85 kcal/mol - (CH₃)₂CH—CH₃: 351 kJ/mol, 84 kcal/mol **Bonds to Methyl (CH₃):** - CH₃—H: 435 kJ/mol, 104 kcal/mol - CH₃—F: 456 kJ/mol, 109 kcal/mol - CH₃—Cl: 351 kJ/mol, 84 kcal/mol - CH₃—Br: 293 kJ
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