42. Identify the major intermediate in the following organic transformation. Cl2, H20 + enantiomer OH A D

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Chapter1: Chemical Foundations
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42. Identify the major intermediate in the following organic transformation.
Cl2, H20
+ enantiomer
ОН
+
CI
OH
B ||
+
A
43. Identify the major product.
Pr-Br, K-OtBu
heat
A
В
44. Reagent ZEUS is reacted with butyl lithium and butanal, which affords
(Z)-2-hexene as the major organic product. Identify reagent ZEUS.
D
A
B
Transcribed Image Text:42. Identify the major intermediate in the following organic transformation. Cl2, H20 + enantiomer ОН + CI OH B || + A 43. Identify the major product. Pr-Br, K-OtBu heat A В 44. Reagent ZEUS is reacted with butyl lithium and butanal, which affords (Z)-2-hexene as the major organic product. Identify reagent ZEUS. D A B
40. Select the molecule
38.6, t
most closely
24.3,t
consistent with the
following 13C NMR
spectrum.
178.6, s
zdo
to
Br
Br
ОН
OH
HO
Br
Br.
HO
A
В
D
41. Two monomeric units are shown for nylon, a polyamide. Predict the
hydrolysis products when nylon is treated with a strong acid and subjected
to hydrolysis.
H
Н.
NH2
A
H2N
„NH2
H2N
НО.
NH2
+
H2N
НО.
NH2
+
OH
H2N
Transcribed Image Text:40. Select the molecule 38.6, t most closely 24.3,t consistent with the following 13C NMR spectrum. 178.6, s zdo to Br Br ОН OH HO Br Br. HO A В D 41. Two monomeric units are shown for nylon, a polyamide. Predict the hydrolysis products when nylon is treated with a strong acid and subjected to hydrolysis. H Н. NH2 A H2N „NH2 H2N НО. NH2 + H2N НО. NH2 + OH H2N
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