4.1 Define the following terms: (a) Polymorphic substance. (b) Hexagonal closest packing.

Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
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4.1 Define the following terms:
(a) Polymorphic substance.
(b) Hexagonal closest packing.
4.2 Consider the cubic diamond crystal:
(a) Define lattice and basis for the cubic diamond crystal structure
(b) Calculate the angle between the tetrahedral bonds of the carbon atoms in the diamond
crystal. (use the cube shown in the figure 4.1)
(c) Calculate the value for the packing coefficient of the diamond structure.
4.3 Derive an expression for the total cohesive energy UT at the equilibrium separation Ro. Assume
that the crystal contains N molecules
Transcribed Image Text:4.1 Define the following terms: (a) Polymorphic substance. (b) Hexagonal closest packing. 4.2 Consider the cubic diamond crystal: (a) Define lattice and basis for the cubic diamond crystal structure (b) Calculate the angle between the tetrahedral bonds of the carbon atoms in the diamond crystal. (use the cube shown in the figure 4.1) (c) Calculate the value for the packing coefficient of the diamond structure. 4.3 Derive an expression for the total cohesive energy UT at the equilibrium separation Ro. Assume that the crystal contains N molecules
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