None 4. What is the order of increasing basicity for the followingreagents?CH₂O-Na+NLiINaHCO3IIIIIH,C C C NatIVA.B.C.D.I

Step 1:Stability of conjugate acid is less => More basicElectronegative: C < N < O Step…

Answered: 4. What is the order of increasing…

Introductory Chemistry: An Active Learning Approach

6th Edition

ISBN:9781305079250

Author:Mark S. Cracolice, Ed Peters

Publisher:Mark S. Cracolice, Ed Peters

Chapter17: Acid-base(proton Transfer) Reactions

Section: Chapter Questions

Problem 10PE

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The following reactions illustrate Brnsted acid-base behavior. Complete each equation. a.HI(aq)+?H3O+(aq)+I(aq) b.NH3(l)+?NH4++NH2 c.H2C2O4(aq)+H2O(l)?+HC2O4(aq) d.H2N2O2(aq)+H2O(l)H3O+(aq)+? e.?+H2O(l)H3O+(aq)+CO32(aq)
Use Table 13-2 to order the following from the strongest to the weakest acid. HClO2,H2O,NH4+,HClO4
35. For each pair of concentrations, tell which represents the more acidic solution. a. [H+]=1.2103Mor[H+]=4.5104M b. [H+]=2.6106Mor[H+]=4.3108M c. [H+]=0.000010Mor[H+]=0.0000010
Consider the following four biological solutions: (1) bile, pH 8.0, (2) blood, pH 7.4, (3) urine, pH 6.0, and (4) gastric juice, pH 1.6. a. Which solution has the lowest [H3O+]? b. Which solution has the lowest [OH]? c. List the solutions in order of decreasing acidity. d. List the solutions in order of increasing basicity.
Gastric juice, the digestive ?uid produced in the stomach, contains hydrochloric acid, HCl, Milk of Magnesia, a suspension of solid Mg(OH)2 in an aqueous medium, is sometimes used to neutralize-excess stomach acid. Write a complete balanced equation for the neutralization reaction, and identify the conjugate acid—base pairs.
Use Table 14.3 to help order the following acids from strongest to weakest HNO3,H2O,NH4+,C5H5NH+
Use Table 13-2 to order the following from the strongest to the weakest base. ClO2,H2O,NH3,ClO4
In each of the following chemical equations, identify the conjugate acid—base pairs. a. HF(aq)+H2O(l)F-(aq)+H3O+(aq)b. CN(aq)+H2O(l)HCN(aq)+OH(aq) c. HCO3-(aq)+H2O(l)H2CO3(aq)+OH-(aq)
75. A conjugate acid-base pair Consists of two substances related by the donating and accepting of a(n) ________
Of the hydrogen halides, only HF is a weak acid. Give a possible explanation.
Salicylic acid, HOC6H4CO2H, and its derivatives have been used as pain relievers for a long time. Salicylic acid occurs in small amounts in the leaves, bark, and roots of some vegetation (most notably historically in the bark of the willow tree). Extracts of these plants have been used as medications for centuries. The acid was first isolated in the laboratory in 1838. (a) Bath functional groups of salicylic acid ionize in water, with Ka=1.0103 for the—CO2H group and 4.201013 for the -OH group. What is the pH of a saturated solution of the acid (solubility = 1.8 g/L).. (b) Aspirin was discovered as a result of efforts to produce a derivative of salicylic acid that would not be irritating to the stomach lining. Aspirin is acetylsalicylic acid, CH3CO2C6H4CO2H. The -CO2H functional group is still present, but its acidity is reduced, Ka=3.0104. What is the pH of a solution of aspirin with the same concentration as a saturated solution of salicylic acid (See Part a). (c) Under some conditions, aspirin reacts with water and forms a solution of salicylic acid and acetic acid: CH3CO2C6H4CO2H(aq)+H2O(l)HOC6H4CO2H(aq)+CH3CO2H(aq) i. Which of the acids, salicylic acid or acetic acid, produces more hydronium ions in such a solution? ii. What are the concentrations of molecules and ions in a solution produced by the hydrolysis of 0.50 g of aspirin dissolved in enough water to give 75 mL of solution?
Rank the compounds in each of the following groups in order of increasing acidity or basicity, as indicated, and explain the order you assign. (a) acidity: HCI, HBr, HI. (b)basicity: H2O, OH-, H-, CI-. (c) basicity: Mg(OH)2, Si(OH)4, ClO3(OH) (Hint: Formula could also be written as HCIO4). (d) acidity: HF, H2O, NH3, CH4

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4. What is the order of increasing basicity for the following reagents? CH₂O-Na+ NLi I NaHCO3 II III H,C C C Nat IV A. B. C. D. I