4. TABLE 13.2 Spectroscopic parameters of some diatomic molecules in the ground electronic state. Molecule B/cm ã,/cm- ã /cm-1 D/cm-! Kve/cm= R(v = 0)/pm Do/kJ-mol-1 De/cm1 432.1 н, н°F H3³CI 79B. 60.8530 74.14 3.0622 4.71 x 10-2 4401.213 121.336 566.2 20.9557 91.68 0.798 2.15 x 10-3 4138.32 89.88 427.8 10.5934 127.46 0.3072 5.319 x 10-4 2990.946 52.819 362.6 8.4649 141.44 0.2333 3.458 x 10-4 2648.975 45.218 н1271 294.7 160.92 6.5122 39.644 0.1689 2.069 x 10- 2309.014 12c160 14N160 14N14N 160160 19F1ºF 35 CI35 Cl 1070.2 112.83 6.122 x 10-6 2169.814 1.9313 13.288 0.0175 626.8 115.08 14.075 1.67195 0.0171 5.4 x 10-6 1904.20 941.6 109.77 5.76 x 10-6 2358.57 14.324 1.9982 0.017 32 493.6 120.75 4.84 x 10-6 11.98 1580.19 1.4456 0.0159 154.6 141.19 11.236 916.64 3.3 x 10-6 0.89019 0.138 47 239.2 198.79 2.675 1.86 x 10-7 559.72 0.001 49 0.2440 79 BrBr 190.1 79 228.11 1.0774 0.000 3187 2.09 × 10-8 325.321 0.0821 0.03737 0.000 1138 4.25 x 10-9 0.5165 0.004 358 8.77 x 10-7 148.8 266.63 [127ן127 35 C1 ºF 0.6147 214.502 252.5 786.15 6.161 162.83 71.1 0.7255 307.89 23 Na23 Na 159.125 0.000 8736 5.81 × 10-7 0.1547 39 к 39К 53.5 8.63 x 10-8 92.021 0.2829 390.51 0.05674 0.000 165
4. TABLE 13.2 Spectroscopic parameters of some diatomic molecules in the ground electronic state. Molecule B/cm ã,/cm- ã /cm-1 D/cm-! Kve/cm= R(v = 0)/pm Do/kJ-mol-1 De/cm1 432.1 н, н°F H3³CI 79B. 60.8530 74.14 3.0622 4.71 x 10-2 4401.213 121.336 566.2 20.9557 91.68 0.798 2.15 x 10-3 4138.32 89.88 427.8 10.5934 127.46 0.3072 5.319 x 10-4 2990.946 52.819 362.6 8.4649 141.44 0.2333 3.458 x 10-4 2648.975 45.218 н1271 294.7 160.92 6.5122 39.644 0.1689 2.069 x 10- 2309.014 12c160 14N160 14N14N 160160 19F1ºF 35 CI35 Cl 1070.2 112.83 6.122 x 10-6 2169.814 1.9313 13.288 0.0175 626.8 115.08 14.075 1.67195 0.0171 5.4 x 10-6 1904.20 941.6 109.77 5.76 x 10-6 2358.57 14.324 1.9982 0.017 32 493.6 120.75 4.84 x 10-6 11.98 1580.19 1.4456 0.0159 154.6 141.19 11.236 916.64 3.3 x 10-6 0.89019 0.138 47 239.2 198.79 2.675 1.86 x 10-7 559.72 0.001 49 0.2440 79 BrBr 190.1 79 228.11 1.0774 0.000 3187 2.09 × 10-8 325.321 0.0821 0.03737 0.000 1138 4.25 x 10-9 0.5165 0.004 358 8.77 x 10-7 148.8 266.63 [127ן127 35 C1 ºF 0.6147 214.502 252.5 786.15 6.161 162.83 71.1 0.7255 307.89 23 Na23 Na 159.125 0.000 8736 5.81 × 10-7 0.1547 39 к 39К 53.5 8.63 x 10-8 92.021 0.2829 390.51 0.05674 0.000 165
Chemistry
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Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
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Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Look up the actual values of the molar heat capacities, C_p and C_v, in an appropriate source and calculate gamma (gamma = C_p/C_v) for all the following gases: Ar, CO_2, N_2, SO_2.
Transcribed Image Text:4.
TABLE 13.2
Spectroscopic parameters of some diatomic molecules in the ground electronic state.
Molecule B/cm ã,/cm-
ã /cm-1
D/cm-!
Kve/cm= R(v = 0)/pm Do/kJ-mol-1
De/cm1
432.1
н,
н°F
H3³CI
79B.
60.8530
74.14
3.0622
4.71 x 10-2 4401.213 121.336
566.2
20.9557
91.68
0.798
2.15 x 10-3 4138.32
89.88
427.8
10.5934
127.46
0.3072
5.319 x 10-4 2990.946
52.819
362.6
8.4649
141.44
0.2333
3.458 x 10-4 2648.975
45.218
н1271
294.7
160.92
6.5122
39.644
0.1689
2.069 x 10- 2309.014
12c160
14N160
14N14N
160160
19F1ºF
35 CI35 Cl
1070.2
112.83
6.122 x 10-6 2169.814
1.9313
13.288
0.0175
626.8
115.08
14.075
1.67195 0.0171
5.4 x 10-6
1904.20
941.6
109.77
5.76 x 10-6 2358.57
14.324
1.9982
0.017 32
493.6
120.75
4.84 x 10-6
11.98
1580.19
1.4456
0.0159
154.6
141.19
11.236
916.64
3.3 x 10-6
0.89019 0.138 47
239.2
198.79
2.675
1.86 x 10-7
559.72
0.001 49
0.2440
79 BrBr
190.1
79
228.11
1.0774
0.000 3187 2.09 × 10-8
325.321
0.0821
0.03737 0.000 1138 4.25 x 10-9
0.5165 0.004 358 8.77 x 10-7
148.8
266.63
[127ן127
35 C1 ºF
0.6147
214.502
252.5
786.15
6.161
162.83
71.1
0.7255
307.89
23 Na23 Na
159.125
0.000 8736 5.81 × 10-7
0.1547
39 к 39К
53.5
8.63 x 10-8
92.021
0.2829
390.51
0.05674 0.000 165
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