4. Solid nickel carbonate (NiCO3) is pretty insoluble in water, as are many metal carbonates. But it is much more soluble in aqueous solutions of NaCN because nickel (II) reacts with cyanide anion to form a tetracyanonickelate complex. Nickel (II) is also mildly acidic, but you can ignore that part of the system if you want. A.) Write the balanced chemical equations AND the corresponding equilibrium constant expressions that explain the solubility behavior of nickel carbonate in aqueous 0.1 M NaCN. B.) Write the charge balance expression that applies to the BCE's you wrote above. C.) Write one mass balance expression for the system.
4. Solid nickel carbonate (NiCO3) is pretty insoluble in water, as are many metal carbonates. But it is much more soluble in aqueous solutions of NaCN because nickel (II) reacts with cyanide anion to form a tetracyanonickelate complex. Nickel (II) is also mildly acidic, but you can ignore that part of the system if you want. A.) Write the balanced chemical equations AND the corresponding equilibrium constant expressions that explain the solubility behavior of nickel carbonate in aqueous 0.1 M NaCN. B.) Write the charge balance expression that applies to the BCE's you wrote above. C.) Write one mass balance expression for the system.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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Transcribed Image Text:4. Solid nickel carbonate (NiCO3) is pretty insoluble in water, as are many metal carbonates.
But it is much more soluble in aqueous solutions of NaCN because nickel (II) reacts with
cyanide anion to form a tetracyanonickelate complex. Nickel (II) is also mildly acidic, but
you can ignore that part of the system if you want.
A.) Write the balanced chemical equations AND the corresponding equilibrium
constant expressions that explain the solubility behavior of nickel carbonate in
aqueous 0.1 M NaCN.
B.) Write the charge balance expression that applies to the BCE's you wrote above.
C.) Write one mass balance expression for the system.
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