None 4. Nominally pure water in the laboratory generally contains dissolved CO2, in itshydrated form: H2CO3(aq), which ionizes in accord with:=1) H2CO3 HCO3 + H+K₁ = 4.47 x 10-7 M and2) HCO3 CO₂²- + H+K2 4.68 x 10-11 MThe pH is measured to be 5.5. The contribution of the ionization of water itselfto the H+ ion concentration may be neglected. Evaluate the equilibriummolarities of the species H+, H2CO3, HCO3 and CO2²-.

To evaluate the equilibrium molarities of the species H+ , HCO3-, H2CO3 &CO22-, we can use the…

Answered: 4. Nominally pure water in the…

Fundamentals Of Analytical Chemistry

9th Edition

ISBN:9781285640686

Author:Skoog

Publisher:Skoog

Chapter21: Potentiometry

Section: Chapter Questions

Problem 21.22QAP

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Sketch a titration curve for the titration of potassium hydroxide with HCl, both 0.100 M. Identify three regions in which a particular chemical species or system dominates the acid-base equilibria.
Amino acids are an important group of compounds. At low pH, both the carboxylic acid group (CO2H) and the amine group (NHR) are protonated. However, as the pH of the solution increases (say, by adding base), the carboxylic acid proton is removed, usually at a pH between 2 and 3. In a middle range of pHs, therefore, the amine group is protonated, but the carboxylic acid group has lost the proton. (This is called a zwitterion.) At more basic pH values, the amine proton is dissociated. What is the pH of a 0.20 M solution of alanine hydrochloride, [NH3CHCH3CO2H]Cl?
You have a solution of the weak acid HA and add some of the salt NaA to it. What are the major species in the solution? What do you need to know to calculate the pH of the solution, and how would you use this information? How does the pH of the solution of just the HA compare with that of the final mixture? Explain.
Given three acid-base indicatorsâ€”methyl orange (end point at pH 4), bromthymol blue (end point at pH 7), and phenolphthalein (end point at pH 9)â€”which would you select for the following acid-base titrations? (a) perchloric acid with an aqueous solution of ammonia (b) nitrous acid with lithium hydroxide (c) hydrobromic acid with strontium hydroxide (d) sodium fluoride with nitric acid
Ka for formic acid is 1.7 104 at 25C. A buffer is made by mixing 529 mL of 0.465 M formic acid, HCHO2, and 494 mL of 0.524 M sodium formate, NaCHO2. Calculate the pH of this solution at 25C after 110 mL of 0.152 M HCl has been added to this buffer.
Sketch the titration curve for a weak acid titrated by a strong base. When performing calculations concerning weak acidstrong base titrations, the general two-slep procedure is to solve a stoichiometry problem first, then to solve an equilibrium problem to determine the pH. What reaction takes place in the stoichiometry part of the problem? What is assumed about this reaction? At the various points in your titration curve, list the major species present after the strong base (NaOH, for example) reacts to completion with the weak acid, HA. What equilibrium problem would you solve at the various points in your titration curve to calculate the pH? Why is pH 7.0 at the equivalence point of a weak acid-strong base titration? Does the pH at the halfway point to equivalence have to be less than 7.0? What does the pH at the halfway point equal? Compare and contrast the titration curves for a strong acidstrong base titration and a weak acidstrong base titration.
What is an acidbase indicator? Define the equivalence (stoichiometric) point and the end point of a titration. Why should you choose an indicator so that the two points coincide? Do the pH values of the two points have to be within 0.01 pH unit of each other? Explain.
Determine the dominant acid-base equilibrium that results when each of the following pairs of solutions is mixed. Indicate the equilibrium by writing 1 for a strong acid, 3 for a weak acid, 4 for an acidic buffer, 7 for a neutral solution, 10 for a basic buffer, 11 for a weak base, and 13 for a strong base. (a) 10.0 mL of 0.15 M NaOH + 15.0 mL of 0.10 M HNO3 (b) 25.0 mL of 0.10 M HCl + 10.0 mL of 0.25 M NH3 (c) 50.0 mL of 0.050 M NaOH + 50.0 mL of 0.10 M NH3 (d) 50.0 mL of 0.10 M NH3 + 50.0 mL of 0.05 M HCl
Please complete the calculation of the pH of the equivalence point all numbers required are here Concentration of NaOH solution = 0.1 mol dm3. Mean titre (NaOH solution) = 17.95 cm³. Amount of NaOH = 0.00180 moles. Molar ratio of NaOH:aspirin = 1:1. Amount of aspirin = 0.00180 moles. Mass of aspirin (in titration) = 0.324 g. Mass of aspirin (per tablet) = 0.324 g. %3D
Give a clear handwritten answer with explanation.....
A buffer system is prepared by combining 0.603 moles of ammonium chloride (NH4CI) and 0.713 moles of ammonia (NH3). What will the solution pH be if 0.239 moles of the nitric acid (HNO3) is added to the solution. Nitric acid is a strong acid. The K₁ of ammonia is 1.8 x 10-5. (Two decimal places)
A 0.263 g sample of Na2CO3 requires 28.35 mL of HCl to completely react with it. What is the pH of the HCl?2HCl (aq) + Na2CO3(aq) --> 2NaCl (aq) + H2O (l) +CO2 (g) please clealry write out each step that you are doing in detail and explain why

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