4. Consider the reaction of ammonium ions (NH*) and nitrite ions (NO,"), shown in Equation 19. NH,*(aq) + NO," (aq) → N2(g) + 2 H20(!) (Eq. 19) Solutions containing NH,* and NO, were mixed in various quantities and the following rate data at a constant temperature were obtained: initial NO2 initial rate for initial NH concentration, determination concentration, formation of N2 number moVL mo/L mol/L's 7.50 × 10-3 1.50 x 10-2 1.50 x 10-2 3.04 x 10-7 6.08 x 10-7 1.22 x 10-6 0.150 0.150 0.300 (c) Calculate the rate constant, k, for the reaction of NH,* and NO,. (a) Use the method of initial rates to find the or- der of the reaction with respect to NH. (b) Use the method of initial rates to find the order of the reaction with respect to NO2. (d) Write the rate equation for the reaction of NH, and NO,.
4. Consider the reaction of ammonium ions (NH*) and nitrite ions (NO,"), shown in Equation 19. NH,*(aq) + NO," (aq) → N2(g) + 2 H20(!) (Eq. 19) Solutions containing NH,* and NO, were mixed in various quantities and the following rate data at a constant temperature were obtained: initial NO2 initial rate for initial NH concentration, determination concentration, formation of N2 number moVL mo/L mol/L's 7.50 × 10-3 1.50 x 10-2 1.50 x 10-2 3.04 x 10-7 6.08 x 10-7 1.22 x 10-6 0.150 0.150 0.300 (c) Calculate the rate constant, k, for the reaction of NH,* and NO,. (a) Use the method of initial rates to find the or- der of the reaction with respect to NH. (b) Use the method of initial rates to find the order of the reaction with respect to NO2. (d) Write the rate equation for the reaction of NH, and NO,.
Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
Section: Chapter Questions
Problem 1RQ: Define and explain the differences between the following terms. a. law and theory b. theory and...
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