4. Consider an equilibrium mixture of the following chemical reaction : Fe"(aq) + SCN (aq) Fe(SCN)"(aq) yellow colourless deep red (a) Write an expression for the equilibrium constant Kc for the reaction. (b) At a certain temperature, the equilibrium constant Kc for the reaction is 1.08 x 10° dm mol*. The equilibrium mixture is prepared by mixing 20.0 cm of 0.030 M Fe(NO3)3(aq) with 10.0 cm of 0.030 M KSCN(aq) in an acidic medium. Calculate the concentration of Fe(SCN)²*(aq) in the equilibrium mixture at that temperature. (c) It is known that the equilibrium constant Kc increases when temperature increases. Suggest and explain whether the enthalpy change of the reaction is positive, negative or zero.

Chemistry for Engineering Students
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Chapter12: Chemical Equilibrium
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4.
Consider an equilibrium mixture of the following chemical reaction :
Fe"(aq) + SCN (aq) – Fe(SCN)³"(aq)
yellow colourless
deep red
(a) Write an expression for the equilibrium constant Kc for the reaction.
(b) At a certain temperature, the equilibrium constant Kc for the reaction is 1.08 x 10° dm³ mol1. The
equilibrium mixture is prepared by mixing 20.0 cm³ of 0.030 M Fe(NO3)3(aq) with 10.0 cm³ of 0.030
M KSCN(aq) in an acidic medium. Calculate the concentration of Fe(SCN)²*(aq) in the equilibrium
mixture at that temperature.
(c) It is known that the equilibrium constant Kc increases when temperature increases. Suggest and
explain whether the enthalpy change of the reaction is positive, negative or zero.
(d) When a little amount of Na,SO3(s) is added to the equilibrium mixture, the colour of the mixture
becomes paler. Explain this observation.
Transcribed Image Text:4. Consider an equilibrium mixture of the following chemical reaction : Fe"(aq) + SCN (aq) – Fe(SCN)³"(aq) yellow colourless deep red (a) Write an expression for the equilibrium constant Kc for the reaction. (b) At a certain temperature, the equilibrium constant Kc for the reaction is 1.08 x 10° dm³ mol1. The equilibrium mixture is prepared by mixing 20.0 cm³ of 0.030 M Fe(NO3)3(aq) with 10.0 cm³ of 0.030 M KSCN(aq) in an acidic medium. Calculate the concentration of Fe(SCN)²*(aq) in the equilibrium mixture at that temperature. (c) It is known that the equilibrium constant Kc increases when temperature increases. Suggest and explain whether the enthalpy change of the reaction is positive, negative or zero. (d) When a little amount of Na,SO3(s) is added to the equilibrium mixture, the colour of the mixture becomes paler. Explain this observation.
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