4. Calculate the effective mass of C¹20 and C¹³0.

Chemistry
10th Edition
ISBN:9781305957404
Author:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Publisher:Steven S. Zumdahl, Susan A. Zumdahl, Donald J. DeCoste
Chapter1: Chemical Foundations
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4. Calculate the effective mass of C¹2O and C¹³0.
5. Look in the literature and Appendix 2 of the practical notes to find values for the molecular
parameters k, Ic, De and vibrational frequency. Describe a general relationship between bond
order and the magnitude of k, De, re and vibrational frequency for diatomic molecules.
Transcribed Image Text:4. Calculate the effective mass of C¹2O and C¹³0. 5. Look in the literature and Appendix 2 of the practical notes to find values for the molecular parameters k, Ic, De and vibrational frequency. Describe a general relationship between bond order and the magnitude of k, De, re and vibrational frequency for diatomic molecules.
Appendix 2: Synoptic Table of Molecular Constants5
Bond
NO
HCI
N₂
ICI
0₂
U (cm'¹)
1904.0
2990.6
2358.07
384.2
1580.36
Order
2
1
3
1
2
Re (pm)
115.1
127.4
109.8
232.1
120.8
k (N.m¹¹)
1595
516
2294
238
1177
D. (kJ/mol)
at 298 K
625
431
945
210
497
Transcribed Image Text:Appendix 2: Synoptic Table of Molecular Constants5 Bond NO HCI N₂ ICI 0₂ U (cm'¹) 1904.0 2990.6 2358.07 384.2 1580.36 Order 2 1 3 1 2 Re (pm) 115.1 127.4 109.8 232.1 120.8 k (N.m¹¹) 1595 516 2294 238 1177 D. (kJ/mol) at 298 K 625 431 945 210 497
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