4. Calcium carbide reacts with water to form acetylene, a gas used in welding. How many KJ of heat are evolved in the reaction of 3.50 kg of CaC2 with 1.25 L of H2O? (Ans:-4440KJ) CaC₂(s) + 2H₂O(1) C2H2(g) + Ca(OH)2(s) AH -128.0 KJ/mol (Strategy: this is a limiting reagent problem. a) convert kg of CaC2 to g and then to mols; b) find the amount of energy released using AH; c) convert L of H2O to kg and then to g of H2O and find mols; d) find the amount of energy released using AH; the lower amount of energy released is the correct answer).

4. Calcium carbide reacts with water to form acetylene, a gas used in welding. How many KJ of heat are evolved in the reaction of 3.50 kg of CaC2 with 1.25 L of H2O? (Ans:-4440KJ) CaC₂(s) + 2H₂O(1) C2H2(g) + Ca(OH)2(s) AH -128.0 KJ/mol (Strategy: this is a limiting reagent problem. a) convert kg of CaC2 to g and then to mols; b) find the amount of energy released using AH; c) convert L of H2O to kg and then to g of H2O and find mols; d) find the amount of energy released using AH; the lower amount of energy released is the correct answer).

Chemistry for Engineering Students

4th Edition

ISBN:9781337398909

Author:Lawrence S. Brown, Tom Holme

Publisher:Lawrence S. Brown, Tom Holme

Chapter9: Energy And Chemistry

Section: Chapter Questions

Problem 9.53PAE: 9.53 Using these reactions, find the standard enthalpy change for the formation of 1 mol of PhO(s)...

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9.53 Using these reactions, find the standard enthalpy change for the formation of 1 mol of PhO(s) from lead metal and oxygen gas. PbO(s)+C(graphite)Pb(s)+CO(g) H = 106.8 kJ 2C(graphite)+O2(g)2CO(g) H= -221.0 kJ If 250 g of lead reacts with oxygen to form lead(II) oxide, what quantity of thermal energy (in kJ) is ahsorhed or evolved?
Combustion of table sugar produces CO2(g) and H2O( l). When 1.46 g table sugar is combusted in a constant-volume (bomb) calorimeter, 24.00 kJ of heat is liberated. a. Assuming that table sugar is pure sucrose, C12H22O11 (s), write the balanced equation for the combustion reaction. b. Calculate E in kJ/mol C12H22O11 for the combustion reaction of sucrose.
You wish to heat water to make coffee. How much heat (in joules) must be used to raise the temperature of 0.180 kg of tap water (enough for one cup of coffee) from 30C to 96C (near the ideal brewing temperature)? Assume the specific heat is that of pure water, 4.18 J/(gC).
Given the following (hypothetical) thermochemical equations: A+B2C;H=447kJA+3D2E;H=484kJ2D+B2F;H=429kJ Calculate H, in kJ, for the equation 4E+5B4C+6F
Given 2Cr2O3(s)4Cr(s)+3O2(g)H=+2269.4kJ (a) What is the heat of formation of chromium(III) oxide? (b) What is H for the formation of 13.65 g of chromium (III) oxide?
Chlorine trifluoride is a toxic, intensely reactive gas. It was used in World War II to make incendiary bombs. It reacts with ammonia and forms nitrogen, chlorine, and hydrogen fluoride gases. When two moles of chlorine trifluoride react, 1196 kJ of heat are evolved. (a) Write a thermochemical equation for the reaction. (b) What is Hf for ClF3?
A typical fat in the body is glyceryl trioleate, C57H104O6. When it is metabolized in the body, it combines with oxygen to produce carbon dioxide, water, and 3.022104 kJ of heat per mole of fat. (a) Write a balanced thermochemical equation for the metabolism of fat. (b) How many kilojoules of energy must be evolved in the form of heat if you want to get rid of five pounds of this fat by combustion? (c) How many nutritional calories is this? (1 nutritional calories =1103 calories)
9.104 An engineer is using sodium metal as a cooling agent in a design because it has useful thermal properties. Looting up the heat capacity, the engineer finds a value of 28.2 J mol-l °C-l. Carelessly, he wrote this number down without units. As a result, it was later taken as specific heat. (a) What would he the difference between these two values? (b) Would the engineer overestimate the ability of sodium to remove heat from the system or underestimate it because of this error? Be sure to explain your reasoning.
A student performing a calorimetry experiment combined 100.0 ml. of 0.50 M HCI and 100.0 ml. of 0.50 M NaOH in a StyrofoamTM cup calorimeter. Both solutions were initially at 20.0 C, but when the two were mixed, the temperature rose to 23.2 C (a) Suppose the experiment is repeated in the same calorimeter but this time using 200 mL of 0.50 M HCl and 200.0 ml of 0.50 M NaOH. WIII the AT observed be greater than, less than, or equal to that in the first experiment, and why? (b) Suppose that the experiment is repeated once again in the same calorimeter, this time using 100 mL of 1.00 M HCI and 100.0 ml. of 1.00 M NaOH. Will the T observed be greater than, less than, or equal to that in the first experiment, and why?
The decomposition of ozone, O3, to oxygen, O2, is an exothermic reaction. What is the sign of q? If you were to touch a flask in which ozone is decomposing to oxygen, would you expect the flask to feel warm or cool?
9.18 Calculate (a) q when a system does 54J of work and its energy decreases by 72 J and (b) E for a gas that releases 38 J of heat and has 102 J of work done on it.
Give the definition of the standard enthalpy of formation for a substance. Write separate reactions for the formation of NaCl, H2O , C6H12O6, and PbSO4 that have H values equal to Hf for each compound.

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